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Manganese(II,III) Oxide

CAS #:

Linear Formula:

Mn3O4

MDL Number:

MFCD00016218

EC No.:

215-266-5

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Manganese(II,III) Oxide
MN23-OX-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Manganese(II,III) Oxide
MN23-OX-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Manganese(II,III) Oxide
MN23-OX-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Manganese(II,III) Oxide
MN23-OX-05
Pricing > SDS > Data Sheet >

Manganese(II,III) Oxide Properties (Theoretical)

Compound Formula Mn3O4
Molecular Weight 228.81
Appearance Powder
Melting Point N/A
Boiling Point 760 °C (1400 °C)
Density 4.8 g/cm3
Exact Mass 230.809
Monoisotopic Mass 230.809

Manganese(II,III) Oxide Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Precautionary Statements N/A
Flash Point Not applicable
Risk Codes N/A
Safety Statements N/A
RTECS Number OP0895000
Transport Information NONH
WGK Germany nwg

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/20/2018
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Manganese(II,III) Oxide

Product Number: All applicable American Elements product codes, e.g. MN23-OX-02 , MN23-OX-03 , MN23-OX-04 , MN23-OX-05

CAS #: 1317-35-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Not a hazardous substance or mixture.
GHS Label elements, including precautionary statements
Not a hazardous substance or mixture.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Formula: Mn3O4
Molecular weight: 228.81 g/mol
CAS-No.: 1317-35-7
EC-No.: 215-266-5


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Manganese/manganese oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing Vapors, mist or gas.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: Powder or solid in various forms
Colour: brown
Odor
No data available
Odor Threshold
No data available
pH
No data available
Melting point/freezing point
Melting point/freezing point: > 450 °C (> 842 °F)
Initial boiling point and boiling range
No data available
Flash point
N/A
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapor pressure
No data available
Vapor density
No data available
Relative density
4.8 g/cm3 at 25 °C (77 °F)
Water solubility
No data available
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products-No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
LD50 Oral-Rat-female-> 2,000 mg/kg
(Fixed Dose Method)
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
Skin-Rabbit
Result: No skin irritation
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes-Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitisation-Mouse
Result: Did not cause sensitisation on laboratory animals.
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
Reproductive toxicity-Mouse-Oral
Paternal Effects: Testes, epididymis, sperm duct. Paternal Effects: Prostate, seminal vessicle, Cowper's gland, accessory glands.
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: OP0895000
Men exposed to manganese dusts showed a decrease in fertility.
Chronic manganese poisoning primarily involves the central nervous system. Early symptoms include languor, sleepiness and weakness in the legs. A stolid mask-like appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to fall
in walking are findings in more advanced cases. High incidence of pneumonia has been found in workers exposed to the dust or fume of some manganese compounds.
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Toxicity to daphnia and other aquatic invertebrates
static test EC50-Daphnia magna (Water flea)-> 1.6 mg/l-48 h(OECD Test Guideline 202)
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.


SECTION 14. EXPOSURE CONTROLS/PERSONAL PROTECTION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Trimanganese tetraoxide
CAS-No.
1317-35-7
Revision Date
1994-04-01
SARA 311/312 Hazards
Chronic Health Hazard
Massachusetts Right To Know Components
Trimanganese tetraoxide
CAS-No.
1317-35-7
Revision Date
1994-04-01
Pennsylvania Right To Know Components
Trimanganese tetraoxide
CAS-No.
1317-35-7
Revision Date
1994-04-01
New Jersey Right To Know Components
Trimanganese tetraoxide
CAS-No.
1317-35-7
Revision Date
1994-04-01
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Manganese(II,III) Oxide

Oxide IonManganese Oxide is a highly insoluble thermally stable Manganese source suitable for glass, optic and ceramic applications. Manganese oxide is a blackish/ brown solid andHigh Purity (99.999%) Manganese Oxide (MnO) Powder the primary natural source of manganese. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. They are compounds containing at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advanced electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic conductivity. Metal oxide compounds are basic anhydrides and can therefore react with acids and with strong reducing agents in redox reactions. Manganese Oxide is also available in pellets, pieces, powder, sputtering targets, tablets, andnanopowder (from American Elements' nanoscale production facilities). Manganese Oxide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. Additional technical, research and safety (MSDS) information is available.

Manganese(II,III) Oxide Synonyms

Manganese(II,III) oxide, manganomanganic oxide, Trimanganese tetroxide, Oxo-(oxomanganiooxy)manganese, Trimanganese tetraoxide, M 34 (pigment), Dimanganese trioxide, Keto-(ketomanganiooxy)manganese,

Chemical Identifiers

Linear Formula Mn3O4
MDL Number MFCD00016218
EC No. 215-266-5
Beilstein Registry No. N/A
Pubchem CID 14825
IUPAC Name hydroxy(oxo)manganese; manganese
SMILES [Mn].O=[Mn]O.O=[Mn]O
InchI Identifier InChI=1S/3Mn.2H2O.2O/h;;;2*1H2;;/q;2*+1;;;;/p-2
InchI Key AMWRITDGCCNYAT-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

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October 20, 2018
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