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Manganese Iron Oxide Nanoparticles / Nanopowder

MnFe2O4

MDL Number:

N/A

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Manganese Iron Oxide Nanopowder
MN-FEO-02-NP
Pricing > SDS > Data Sheet >
(3N) 99.9% Manganese Iron Oxide Nanopowder
MN-FEO-03-NP
Pricing > SDS > Data Sheet >
(4N) 99.99% Manganese Iron Oxide Nanopowder
MN-FEO-04-NP
Pricing > SDS > Data Sheet >
(5N) 99.999% Manganese Iron Oxide Nanopowder
MN-FEO-05-NP
Pricing > SDS > Data Sheet >

Manganese Iron Oxide Nanoparticles / Nanopowder Properties

Compound Formula

Fe2MnO4

Molecular Weight

230.63

Appearance

Brown to Black Powder

Melting Point

> 300 °C

Boiling Point

N/A

Density

N/A

Exact Mass

230.787579

Monoisotopic Mass

230.787579

Manganese Iron Oxide Nanoparticles / Nanopowder Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information N/A

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 08/17/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Manganese Iron Oxide Nanoparticles / Nanopowder

Product Number: All applicable American Elements product codes, e.g. MN-FEO-02-NP , MN-FEO-03-NP , MN-FEO-04-NP , MN-FEO-05-NP

CAS #: 12063-10-4

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
Not a hazardous substance or mixture.
2.2 GHS Label elements, including precautionary statements
Not a hazardous substance or mixture.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Synonyms : Manganese ferrite
Iron manganese oxide
Iron manganese spinel
Formula : MnFe2O4
Molecular weight : 230.63 g/mol
CAS-No. : 12063-10-4
EC-No. : 269-056-3
Hazardous components
Component Classification Concentration
Iron manganese oxide
<= 100 %


SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
General advice
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Iron oxides, Manganese/manganese oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapours, mist or gas.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
Components with workplace control parameters
Component CAS-No. Value Control
parameters
Basis
Iron manganese
oxide
12063-10-4 C 5.000000
mg/m3
USA. Occupational Exposure Limits
(OSHA) - Table Z-1 Limits for Air
Contaminants
Remarks Ceiling limit is to be determined from breathing-zone air samples.
TWA 0.200000
mg/m3
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Adopted values or notations enclosed are those for which changes
are proposed in the NIC
See Notice of Intended Changes (NIC)
varies
TWA 1.000000
mg/m3
USA. NIOSH Recommended
Exposure Limits
ST 3.000000
mg/m3
USA. NIOSH Recommended
Exposure Limits
TWA 0.100000
mg/m3
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
2015 Adoption
varies
TWA 0.020000
mg/m3
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
2015 Adoption
varies
C 5 mg/m3 USA. Occupational Exposure Limits
(OSHA) - Table Z-1 Limits for Air
Contaminants
Ceiling limit is to be determined from breathing-zone air samples.
TWA 0.1 mg/m3 USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Not classifiable as a human carcinogen
varies
TWA 0.02 mg/m3 USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Not classifiable as a human carcinogen
varies
TWA 1 mg/m3 USA. NIOSH Recommended
Exposure Limits
ST 3 mg/m3 USA. NIOSH Recommended
Exposure Limits
8.2 Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as
NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and
to the specific work-place., The type of protective equipment must be selected according to the concentration
and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type
N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under
appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing point Melting point/range: > 300 °C (> 572 °F)
f) Initial boiling point and boiling range No data available
g) Flash point Not applicable
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower flammability or explosive limits No data available
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density No data available
n) Water solubility No data available
o) Partition coefficient: noctanol/water No data available
p) Auto-ignition temperature No data available
q) Decomposition temperature No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
Men exposed to manganese dusts showed a decrease in fertility. Chronic manganese poisoning primarily involves the
central nervous system. Early symptoms include languor, sleepiness and weakness in the legs. A stolid mask-like
appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to fall
in walking are findings in more advanced cases. High incidence of pneumonia has been found in workers exposed to
the dust or fume of some manganese compounds., To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Stomach - Irregularities - Based on Human Evidence
Stomach - Irregularities - Based on Human Evidence


SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Iron manganese oxide
CAS-No.
12063-10-4
Revision Date
2007-07-01
SARA 311/312 Hazards
Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Iron manganese oxide
CAS-No.
12063-10-4
Revision Date
2007-07-01
New Jersey Right To Know Components
Iron manganese oxide
CAS-No.
12063-10-4
Revision Date
2007-07-01
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Manganese Iron Oxide Nanoparticles / Nanopowder

High Purity, D50 = +10 nanometer (nm) by SEMOxide IonManganese Iron Oxide Nanopowder nanodots or nanoparticles are high surface area particles. Mangasorb™ nano scale Manganese Iron Oxide Nanoparticles are typically 5 - 100 nanometers (nm) with specific surface area (SSA) in the 25 - 50 m2/g range. Nano Manganese Iron Oxide Particles are also available in Ultra high purity and high purity and coated and dispersed forms. They are also available as a dispersion through the AE Nanofluid production group. Nanofluids are generally defined as suspended nanoparticles in solution either using surfactant or surface charge technology. Nanofluid dispersion and coating selection technical guidance is also available. Other nanostructures include nanorods, nanowhiskers, nanohorns, nanopyramids and other nanocomposites. Surface functionalized nanoparticles allow for the particles to be preferentially adsorbed at the surface interface using chemically bound polymers.

Manganese Iron Oxide Nanoparticles / Nanopowder Synonyms

Manganese Ferrite, Bixbyite Manganese Diiron Oxide, Iron manganese oxide, Iron manganese spinel

Manganese Iron Oxide Nanoparticles / Nanopowder Chemical Identifiers

Linear Formula

MnFe2O4

Pubchem CID

19601213

MDL Number

N/A

EC No.

N/A

IUPAC Name

iron(3+); manganese(2+); oxygen(2-)

SMILES

[O-2].[O-2].[O-2].[O-2].[Mn+2].[Fe+3].[Fe+3]

InchI Identifier

1S/2Fe.Mn.4O/q2*+3;+2;4*-2

InchI Key

CUSDLVIPMHDAFT-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Iron products. Iron (atomic symbol: Fe, atomic number: 26) is a Block D, Group 8, Period 4 element with an atomic weight of 55.845. The number of electrons in each of Iron's shells is 2, 8, 14, 2 and its electron configuration is [Ar] 3d6 4s2. Iron Bohr ModelThe iron atom has a radius of 126 pm and a Van der Waals radius of 194 pm. Iron was discovered by humans before 5000 BC. In its elemental form, iron has a lustrous grayish metallic appearance. Iron is the fourth most common element in the Earth's crust and the most common element by mass forming the earth as a whole. Iron is rarely found as a free element, since it tends to oxidize easily; it is usually found in minerals such as magnetite, hematite, goethite, limonite, or siderite.Elemental Iron Though pure iron is typically soft, the addition of carbon creates the alloy known as steel, which is significantly stronger.

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

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