Metastable Marcasite-FeS2 as a New Anode Material for Lithium Ion Batteries: CNFs-Improved Lithiation/Delithiation Reversibility and Li-Storage Properties.

Title Metastable Marcasite-FeS2 as a New Anode Material for Lithium Ion Batteries: CNFs-Improved Lithiation/Delithiation Reversibility and Li-Storage Properties.
Authors H.H. Fan; H.H. Li; K.C. Huang; C.Y. Fan; X.Y. Zhang; X.L. Wu; J.P. Zhang
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.7b00578
Abstract

Marcasite (m-FeS2) exhibits higher electronic conductivity than that of pyrite (p-FeS2) because of its lower semiconducting gap (0.4 vs 0.7 eV). Meanwhile, as demonstrates stronger Fe-S bonds and less S-S interactions, the m-FeS2 seems to be a better choice for electrode materials compared to p-FeS2. However, the m-FeS2 has been seldom studied due to its sophisticated synthetic methods until now. Herein, a hierarchical m-FeS2 and carbon nanofibers composite (m-FeS2/CNFs) with grape-cluster structure was designed and successfully prepared by a straightforward hydrothermal method. When evaluated as an electrode material for lithium ion batteries, the m-FeS2/CNFs exhibited superior lithium storage properties with a high reversible capacity of 1399.5 mAh g(-1) after 100 cycles at 100 mA g(-1) and good rate capability of 782.2 mAh g(-1) up to 10 A g(-1). The Li-storage mechanism for the lithiation/delithiation processes of m-FeS2/CNFs was systematically investigated by ex situ powder X-ray diffraction patterns and scanning electron microscopy. Interestingly, the hierarchical m-FeS2 microspheres assembled by small FeS2 nanoparticles in the m-FeS2/CNFs composite converted into a mimosa with leaves open shape during Li(+) insertion process and vice versa. Accordingly, a "CNFs accelerated decrystallization-recrystallization" mechanism was proposed to explain such morphology variations and the decent electrochemical performance of m-FeS2/CNFs.

Citation H.H. Fan; H.H. Li; K.C. Huang; C.Y. Fan; X.Y. Zhang; X.L. Wu; J.P. Zhang.Metastable Marcasite-FeS2 as a New Anode Material for Lithium Ion Batteries: CNFs-Improved Lithiation/Delithiation Reversibility and Li-Storage Properties.. ACS Appl Mater Interfaces. 2017;9(12):1070810716. doi:10.1021/acsami.7b00578

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