Safety Data Sheet

SAFETY DATA SHEET

Date Printed: 05/06/2021
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Methylammonium Triiodoplumbate(II) Precursor

Product Number: All applicable American Elements product codes, e.g. METHAM-3IPB-01-SOL

CAS #: 69507-98-8

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture GHS02 Flame Flam. Liq. 3 H226 Flammable liquid and vapor. GHS08 Health hazard Repr. 1A H360 May damage fertility or the unborn child. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 4 H332 Harmful if inhaled. · Label elements · GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictogram
Flame - GHS02 Exclamation Mark - GHS07 Health Hazard - GHS08
· Signal word Danger · Hazard statements H226 Flammable liquid and vapor. H302+H332 Harmful if swallowed or if inhaled. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapors/spray P281 Use personal protective equipment as required. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Classification system: · NFPA ratings (scale 0 - 4) Health = 4 Fire = 2 Reactivity = 0 · HMIS-ratings (scale 0 - 4) Health = 4 Fire = 2 Reactivity = 0 · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances · CAS No. Description 69507-98-8 Methylammonium triiodoplumbate(II) (40wt% solution in DMF)

SECTION 4. FIRST AID MEASURES

Description of first aid measures · General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately rinse with water. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Immediately call a doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available · Indication of any immediate medical attention and special treatment needed No further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

· Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: Mouth respiratory protective device.

SECTION 6. ACCIDENTAL RELEASE MEASURES

· Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

· Handling: · Precautions for safe handling Thorough dedusting. Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Keep respiratory protective device available. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. · Specific end use(s) No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

· Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: Not required. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Store protective clothing separately. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

· Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Color: Yellow · Odor: undistinguishable · Odor threshold: Not determined. · pH-value: Not applicable. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. · Flash point: 60 °C (140 °F) · Flammability (solid, gaseous): Flammable. · Ignition temperature: Decomposition temperature: Not determined. · Auto igniting: Not determined. · Danger of explosion: Not determined. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure: Not applicable. · Density at 20 °C (68 °F): 1.368 g/cm³ (11.416 lbs/gal) · Relative density Not determined. · Vapor density Not applicable. · Evaporation rate Not applicable. · Solubility in / Miscibility with Water: Insoluble. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. · Solvent content: Organic solvents: 0.0 % VOC content: 0.0 g/l / 0.00 lb/gl Solids content: 100.0 % · Other information No further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

· Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11. TOXICOLOGICAL INFORMATION

· Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) Substance is not listed. · NTP (National Toxicology Program) Substance is not listed. · OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed.

SECTION 12. ECOLOGICAL INFORMATION

· Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

· Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

· UN-Number · DOT, IMDG, IATA UN2929 · UN proper shipping name · DOT, IATA Toxic liquids, flammable, organic, n.o.s. · IMDG TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. · Transport hazard class(es) · DOT · Class 6.1 Toxic substances · Label 6.1, 3 · IMDG · Class 6 · Label 6.1/3 · IATA · Class 6.1 Toxic substances · Label 6.1 (3) · Packing group · DOT, IMDG, IATA I · Environmental hazards: Not applicable. · Special precautions for user Not applicable. · EMS Number: F-E,S-D · Stowage Category B · Stowage Code SW2 Clear of living quarters. · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L · IMDG · Limited quantities (LQ) 0 · Excepted quantities (EQ) Code: E5 Maximum net quantity per inner packaging: 1 g Maximum net quantity per outer packaging: 300 g · UN "Model Regulation": UN 2929 TOXIC LIQUIDS, FLAMMABLE, ORGANIC, N.O.S., 6.1 (3), I

SECTION 15. REGULATORY INFORMATION

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): Substance is not listed. · Section 313 (Specific toxic chemical listings): Substance is not listed. · TSCA (Toxic Substances Control Act): Substance is not listed. · Proposition 65 · Chemicals known to cause cancer: Substance is not listed. · Chemicals known to cause reproductive toxicity for females: Substance is not listed. · Chemicals known to cause reproductive toxicity for males: Substance is not listed. · Chemicals known to cause developmental toxicity: Substance is not listed. · Carcinogenic categories · EPA (Environmental Protection Agency) Substance is not listed. · TLV (Threshold Limit Value established by ACGIH) Substance is not listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed. · GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS02 GHS07 GHS08 · Signal word Danger · Hazard statements H226 Flammable liquid and vapor. H302+H332 Harmful if swallowed or if inhaled. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapors/spray P281 Use personal protective equipment as required. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · National regulations: · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.