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(Methylcyclopentadienyl)manganese(I) Tricarbonyl

(MeCp)Mn(CO)3

CAS #:

Linear Formula:

C5H4CH3Mn(CO)3

MDL Number:

MFCD00001426

EC No.:

235-166-5

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% (Methylcyclopentadienyl)manganese(I) Tricarbonyl
MN-OMX-02
Pricing > SDS > Data Sheet >
(3N) 99.9% (Methylcyclopentadienyl)manganese(I) Tricarbonyl
MN-OMX-03
Pricing > SDS > Data Sheet >
(4N) 99.99% (Methylcyclopentadienyl)manganese(I) Tricarbonyl
MN-OMX-04
Pricing > SDS > Data Sheet >
(5N) 99.999% (Methylcyclopentadienyl)manganese(I) Tricarbonyl
MN-OMX-05
Pricing > SDS > Data Sheet >

(Methylcyclopentadienyl)manganese(I) Tricarbonyl Properties (Theoretical)

Compound Formula C9H7MnO3
Molecular Weight 218.09
Appearance Yellow to dark orange liquid
Melting Point −1 °C
Boiling Point 232-233 °C
Density 1.38 g/mL
Exact Mass 217.977564
Monoisotopic Mass 217.977564
Charge -1

(Methylcyclopentadienyl)manganese(I) Tricarbonyl Health & Safety Information

Signal Word Danger
Hazard Statements H300 + H330-H311-H351
Hazard Codes T
Risk Codes 23/24/25-40
Safety Statements 23-26-36/37/39-45
RTECS Number OP1450000
Transport Information UN 3281 6.1/PG 2
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 01/20/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: (Methylcyclopentadienyl)manganese(I) Tricarbonyl

Product Number: All applicable American Elements product codes, e.g. MN-OMX-02 , MN-OMX-03 , MN-OMX-04 , MN-OMX-05

CAS #: 12108-13-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 2 H300 Fatal if swallowed.
Acute Tox. 2 H310 Fatal in contact with skin.
Acute Tox. 2 H330 Fatal if inhaled.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).

Skull and Crossbones - GHS06Exclamation Mark - GHS07

Hazard pictograms
GHS06 GHS07
Signal word Danger
Hazard-determining components of labeling:
tricarbonyl(methylcyclopentadienyl)manganese
Hazard statements
H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 - 4)
3


Health = 3
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
3


Health = 3
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS # / Substance Name
12108-13-3 tricarbonyl(methylcyclopentadienyl)manganese
Identification number(s)
EC number: 235-166-5


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
If inhaled:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact: Immediately wash with soap and water; rinse thoroughly.
In case of eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed: Do not induce vomiting; immediately call for medical help.
Information for doctor:
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture No data available
Advice for firefighters
Protective equipment: Mouth respiratory protective device.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions: No special measures required.
Methods and materials for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires: Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
12108-13-3 tricarbonyl(methylcyclopentadienyl)manganese
REL Long-term value: 0.2 mg/m3
Skin
TLV Long-term value: 0.2 mg/m3
Skin
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
SProtective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
RTightly sealed goggles


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Liquid
Color: Yellow
Odor: Acrid
Odor threshold: No data available.
pH: No data available.
Melting point/Melting range: -2.2 °C (28 °F)
Boiling point/Boiling range: 233 °C (451 °F)
Flash point: N/A
Flammability (solid, gas): N/A
Ignition temperature:
Decomposition temperature: No data available.
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure at 20 °C (68 °F): 9.3mm (10 hPa (7mm (8 mm Hg)
Density at 20 °C (68 °F): 1.38 g/cm3 (11.516 lbs/gal)
Relative density No data available.
Vapor density No data available.
Evaporation rate No data available.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Solvent content:
Organic solvents: 0.0 %
VOC content: 0.0 g/l / 0.00 lb/gl
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No data available
Incompatible materials: No data available
Hazardous decomposition products: No dangerous decomposition products known.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral LD50 8 mg/kg (rat)
Inhalative LC50/4 h 76 mg/l (rat)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Behavior in environmental systems:
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information: Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN2810
UN proper shipping name
DOT, IATA Toxic, liquids, organic, n.o.s.
IMDG TOXIC LIQUID, ORGANIC, N.O.S.
Transport hazard class(es)
DOT
Class 6.1 Toxic substances
Label 6.1
IMDG, IATA
Class 6.1 Toxic substances
Label 6.1
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: No
Special precautions for user N/A
EMS Number: F-A,S-A
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
IMDG
Limited quantities (LQ) .1L
Excepted quantities (EQ) Code: E4
Maximum net quantity per inner packaging: 1 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": UN 2810 TOXIC, LIQUIDS, ORGANIC, N.O.S., 6.1, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is listed.
Section 313 (Specific toxic chemical listings):
Substance is listed.
TSCA (Toxic Substances Control Act):
Substance is listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS06 GHS07
Signal word Danger
Hazard-determining components of labeling:
tricarbonyl(methylcyclopentadienyl)manganese
Hazard statements
H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About (Methylcyclopentadienyl)manganese(I) Tricarbonyl

(Methylcyclopentadienyl)manganese(I) Tricarbonyl is one of numerous organo-metallic compounds sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. (Methylcyclopentadienyl)manganese(I) Tricarbonyl is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

(Methylcyclopentadienyl)manganese(I) Tricarbonyl Synonyms

Methylcyclopentadienyl manganese tricarbonyl, (Methylcyclopentadienyl)tricarbonylmanganese, Ethyl MMT, MCMT, MMT, NSC 22316, Tricarbonyl(2-methylcyclopentadienyl)manganese, tricarbonyl(methylcyclopentadienyl)manganese, (MeCp)Mn(CO)3; 2-Methylcyclopentadienyl manganese tricarbonyl; tricarbonyl((1, 2, 3, 4, 5-μ)-1-methyl-2, 4-cyclopentadien-1-yl)- manganese

Chemical Identifiers

Linear Formula C5H4CH3Mn(CO)3
MDL Number MFCD00001426
EC No. 235-166-5
Pubchem CID 25511
IUPAC Name carbon monoxide; manganese; 5-methylcyclopenta-1,3-diene
SMILES C[C-]1C=CC=C1.[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mn]
InchI Identifier InChI=1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;/q-1;;;;
InchI Key IYSGJCJSRBFZSZ-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

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January 20, 2019
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