Manganese Sulfate Solution

CAS #:

Linear Formula:

MnSO4• xH2O

MDL Number:

MFCD00149159

EC No.:

232-089-9

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Manganese Sulfate Solution
MN-SAT-02-SOL
Pricing > SDS > Data Sheet >
(3N) 99.9% Manganese Sulfate Solution
MN-SAT-03-SOL
Pricing > SDS > Data Sheet >
(4N) 99.99% Manganese Sulfate Solution
MN-SAT-04-SOL
Pricing > SDS > Data Sheet >
(5N) 99.999% Manganese Sulfate Solution
MN-SAT-05-SOL
Pricing > SDS > Data Sheet >

Manganese Sulfate Solution Properties (Theoretical)

Compound Formula H2MnO5S
Molecular Weight 169.02
Appearance Whitish-Black to Clear Liquid
Melting Point 710° C (1,310° F)
Boiling Point 850° C (1,562° F)
Density 3.25 g/cm3
Solubility in H2O N/A
Exact Mass 168.900339
Monoisotopic Mass 168.900345 Da

Manganese Sulfate Solution Health & Safety Information

Signal Word Warning
Hazard Statements H373-H411
Hazard Codes Xn, N
Risk Codes 48/20/22-51/53
Safety Statements 22-61
RTECS Number OP0893500
Transport Information UN 3077 9/PG 3
WGK Germany 1
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/28/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Manganese Sulfate Solution

Product Number: All applicable American Elements product codes, e.g. MN-SAT-02-SOL , MN-SAT-03-SOL , MN-SAT-04-SOL , MN-SAT-05-SOL

CAS #: 15244-36-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS08 Health hazard
STOT RE 2 H373 May cause damage to the lung, the liver, the blood and the brain through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.
Hazards not otherwise classified No data available.
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)

Health Hazard - GHS08

Hazard pictograms
GHS08
Signal word Warning
Hazard statements
H373 May cause damage to the lung, the liver, the blood and the brain through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P314 Get medical advice/attention if you feel unwell.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1

1
Health (acute effects) = 1
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
15244-36-7 Manganese(II) sulfate hydrate
Identification number(s):
EC number: 232-089-9
Index number: 025-003-00-4


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact: Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed: Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed No information available.
Indication of any immediate medical attention and special treatment needed No information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Metal oxide fume
Sulfur oxides (SOx)
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without official permits.
Methods and material for containment and cleanup: Dispose of contaminated material as waste according to section 13.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure adequate ventilation.
Prevent formation of dust.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s) No information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
15244-36-7 Manganese(II) sulfate hydrate (100.0%)
PEL (USA) Ceiling limit value: 5 mg/m³
as Mn
REL (USA) Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
as Mn
TLV (USA) Long-term value: 0.02* 0.1* mg/m³
as Mn; *respirable **inhalable fraction
EL (Canada) Long-term value: 0.2 mg/m³
as Mn; R
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical general protective and industrial hygiene measures for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes) No data available.
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Crystalline
Color: Pink
Odor: Odorless
Odor threshold: No data available.
pH-value (50 g/l) at 20 °C (68 °F): 3-3.5
Melting point/range: No data available.
Boiling point/range: No data available.
Sublimation temperature / start: No data available.
Flash point: N/A
Flammability (solid, gas): No data available.
Ignition temperature: No data available.
Decomposition temperature: No data available.
Auto igniting: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: N/A.
Density: No data available.
Relative density No data available.
Vapor density N/A.
Evaporation rate N/A.
Solubility in / Miscibility with
Water: Soluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A.
Kinematic: N/A.
Other information No information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions No dangerous reactions known
Conditions to avoid No information available.
Incompatible materials: Oxidizing agents
Hazardous decomposition products:
Metal oxide fume
Sulfur oxides (SOx)


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: N/A
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Irritant to skin and mucous membranes.
Eye irritation or corrosion: Irritating effect.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: N/A
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: N/A
Specific target organ system toxicity - repeated exposure:
May cause damage to the lung, the liver, the blood and the brain through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.
Specific target organ system toxicity - single exposure: N/A
Aspiration hazard: N/A
Subacute to chronic toxicity: N/A
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No information available.
Persistence and degradability: No information available.
Bioaccumulative potential: No information available.
Mobility in soil: No information available.
Ecotoxical effects:
Remark: Toxic for aquatic organisms
Additional ecological information:
General notes:
Do not allow product to reach ground water, water course or sewage system.
Toxic for aquatic organisms
Do not allow material to be released to the environment without official permits.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A.
Other adverse effects No information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation: Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN3077
UN proper shipping name
DOT Environmentally hazardous substances, solid, n.o.s. (Manganese(II) sulfate
hydrate)
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Manganese(II) sulfate hydrate), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Manganese(II) sulfate hydrate)
Transport hazard class(es)
DOT, IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Class 9 (M7) Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant (IMDG): Symbol (fish and tree)
Special marking (ADR): Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
Remarks: Special marking with the symbol (fish and tree).
UN "Model Regulation": UN3077, Environmentally hazardous substances, solid, n.o.s. (Manganese(II)
sulfate hydrate), 9, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS08
Signal word Warning
Hazard statements
H373 May cause damage to the lung, the liver, the blood and the brain through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P314 Get medical advice/attention if you feel unwell.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
15244-36-7 Manganese(II) sulfate hydrate
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Manganese Sulfate Solution

Sulfate IonManganese Sulfate Solutions are moderate to highly concentrated liquid solutions of Manganese Sulfate. They are an excellent source of Manganese Sulfate for applications requiring solubilized Compound Solutions Packaging, Bulk Quantity materials. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles and deposited utilizing sputtering targets and evaporation materials for uses such as solar cells and fuel cells. American Elements can prepare dissolved homogeneous solutions at customer specified concentrations or to the maximum stoichiometric concentration. Packaging is available in 55 gallon drums, smaller units and larger liquid totes. American Elements maintains solution production facilities in the United States, Northern Europe (Liverpool, UK), Southern Europe (Milan, Italy), Australia and China to allow for lower freight costs and quicker delivery to our customers. American Elements metal and rare earth compound solutions have numerous applications, but are commonly used in petrochemical cracking and automotive catalysts, water treatment, plating, textiles, research and in optic, laser, crystal and glass applications. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Manganese Sulfate Powder. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Manganese Sulfate Solution Synonyms

Aqueous Manganous(II) sulfate, Manganous(II) Sulfate, manganese(2+) sulfate

Chemical Identifiers

Linear Formula MnSO4• xH2O
MDL Number MFCD00149159
EC No. 232-089-9
Beilstein/Reaxys No. N/A
Pubchem CID 177577
IUPAC Name manganese(2+); sulfate; hydrate
SMILES [Mn+2].[O-] S([O-]) (=O)=O.O
InchI Identifier InChI=1S/Mn.H2 O4S.H2O/c;1-5(2 ,3)4;/h;(H2,1,2,3, 4);1H2/q+2;;/p-2
InchI Key ISPYRSDWRDQNSW-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Manganese

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

Sulfur

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

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