Monodentate and bridging behaviour of the sulfur-containing ligand 4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine in two discrete zinc(II) complexes with acetylacetonate.

Title Monodentate and bridging behaviour of the sulfur-containing ligand 4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine in two discrete zinc(II) complexes with acetylacetonate.
Authors J. Granifo; R. Gaviño; E. Freire; R. Baggio
Journal Acta Crystallogr C
DOI 10.1107/S010827011203483X
Abstract

The Zn complexes bis(acetylacetonato-?(2)O,O')bis{4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine-?N(1)}zinc(II), [Zn(C(5)H(7)O(2))(2)(C(22)H(17)N(3)S)(2)], (I), and {?-4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine-?(2)N(1):N(1'')}bis[bis(acetylacetonato-?(2)O,O')zinc(II)], [Zn(2)(C(5)H(7)O(2))(4)(C(22)H(17)N(3)S)], (II), are discrete entities with different nuclearities. Compound (I) consists of two centrosymmetrically related monodentate 4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine (L1) ligands binding to one Zn(II) atom sitting on an inversion centre and two centrosymmetrically related chelating acetylacetonate (acac) groups which bind via carbonyl O-atom donors, giving an N(2)O(4) octahedral environment for Zn(II). Compound (II), however, consists of a bis-monodentate L1 ligand bridging two Zn(II) atoms from two different Zn(acac)(2) fragments. Intra- and intermolecular interactions are weak, mainly of the C-H···? and ?-? types, mediating similar layered structures. In contrast to related structures in the literature, sulfur-mediated nonbonding interactions in (II) do not seem to have any significant influence on the supramolecular structure.

Citation J. Granifo; R. Gaviño; E. Freire; R. Baggio.Monodentate and bridging behaviour of the sulfur-containing ligand 4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine in two discrete zinc(II) complexes with acetylacetonate.. Acta Crystallogr C. 2012;68(Pt 10):m26974. doi:10.1107/S010827011203483X

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Sulfur

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

Zinc

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