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Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)

Ni(TMHD)2

CAS #:

Linear Formula:

Ni(OCC(CH3)3CHCOC(CH3)3)2

MDL Number:

MFCD00192348

EC No.:

624-509-8

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
NI-TMHD2-02
Pricing > SDS > Data Sheet >
(2N5) 99.5% Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
NI-TMHD2-025
Pricing > SDS > Data Sheet >
(3N) 99.9% Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
NI-TMHD2-03
Pricing > SDS > Data Sheet >
(3N5) 99.95% Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
NI-TMHD2-035
Pricing > SDS > Data Sheet >
(4N) 99.99% Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
NI-TMHD2-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
NI-TMHD2-05
Pricing > SDS > Data Sheet >

Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) Properties (Theoretical)

Compound Formula C22H38NiO4
Molecular Weight 425.23
Appearance Purple powder or crystals
Melting Point 219-223 °C
Boiling Point 90-100 °C/0.1mm (subl.)
Density N/A
Solubility in H2O Insoluble
Exact Mass 424.212353
Monoisotopic Mass 424.212353

Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) Health & Safety Information

Signal Word Danger
Hazard Statements H302-H312-H332-H350
Hazard Codes T
Precautionary Statements P201-P280-P308+P313
Risk Codes 45-20/21/22
Safety Statements 53-36/37-45
RTECS Number N/A
Transport Information NONH for all modes of transport
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/14/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)

Product Number: All applicable American Elements product codes, e.g. NI-TMHD2-02 02 , NI-TMHD2-025 025 , NI-TMHD2-03 03 , NI-TMHD2-035 035 , NI-TMHD2-04 04 , NI-TMHD2-05 05

CAS #: 14481-08-4

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 4), H332
Acute toxicity, Dermal (Category 4), H312
Carcinogenicity (Category 1B), H350

2.2 GHS Label elements, including precautionary statements

Health Hazard - GHS08Exclamation Mark - GHS07

Pictogram
Signal word Danger
Hazard statement(s)
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled
H350 May cause cancer.
Precautionary statement(s)
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and
understood.
P261 Avoid breathing dust/ fume/ gas/ mist/ Vapors/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you
feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P322 Specific measures (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Synonyms : Ni(TMHD)2
Formula : C22H38NiO4
Molecular Weight : 425.23 g/mol
CAS-No. : 14481-08-4
Hazardous components
Component Classification Concentration
Nickel(II) bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
Acute Tox. 4; Carc. 1B; H302
+ H312 + H332, H350
-


SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available


SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Nickel/nickel oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure adequate
ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved
under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to
the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type
N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the
sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odor no data available
c) Odor Threshold no data available
d) pH no data available
e) Melting point/freezing
point
Melting point/range: 219 - 223 °C (426 - 433 °F) - lit.
f) Initial boiling point and
boiling range
no data available
g) Flash point no data available
h) EVaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower
flammability or
explosive limits
no data available
k) Vapor pressure no data available
l) Vapor density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: noctanol/
water
no data available
p) Auto-ignition
temperature
no data available
q) Decomposition
temperature
no data available
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
9.2 Other safety information
no data available


SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity
no data available
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
This is or contains a component that has been reported to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or
EPA classification.
Possible human carcinogen
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.


SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
no data available
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
no data available


SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a
chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Nickel(II) bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
CAS-No.
14481-08-4
Revision Date
New Jersey Right To Know Components
Nickel(II) bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
CAS-No.
14481-08-4
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)

Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) is one of numerous organo-metallic compounds (also known Organo-Metallic Packaging, Lab Quantity as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) Synonyms

Ni(TMHD)2; bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II); nickel(II) bis(2,2,6,6-tetramethyl-3,5-heptanedio; bis(2,2,6,6-tetramethyl-3,5-heptane-dionato)nickel(II); nickel TMHD; Nickel(II)-DPM; CAS 41749-92-2; C22H40NiO4

Chemical Identifiers

Linear Formula Ni(OCC(CH3)3CHCOC(CH3)3)2
MDL Number MFCD00192348
EC No. 624-509-8
Beilstein Registry No. N/A
Pubchem CID 6432429
IUPAC Name nickel(2+); (Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate
SMILES [Ni+2].[O-]\C(=C/C(=O)C(C)(C)C)C(C)(C)C.[O-]\C(=C/C(=O)C(C)(C)C)C(C)(C)C
InchI Identifier InChI=1S/2C11H20O2.Ni/c2*1-10(2,3)8(12)7-9(13)11(4,5)6;/h2*7,12H,1-6H3;/q;;+2/p-2/b2*8-7-;
InchI Key PIIJAZNTPALBJL-ATMONBRVSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

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