Nickel(II) Formate Dihydrate

CAS #:

Linear Formula:

Ni(HCO2)2•2H2O

MDL Number:

MFCD00153034

EC No.:

222-101-0

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
Nickel(II) Formate Dihydrate
NI2-FMAT-01-P.2HYD
Pricing > SDS > Data Sheet >

Nickel(II) Formate Dihydrate Properties (Theoretical)

Compound Formula C2H6NiO6
Molecular Weight 184.76
Appearance Green powder
Melting Point 130-140 °C
Boiling Point N/A
Density 2.15 g/cm3
Solubility in H2O N/A
Exact Mass 183.951781 g/mol
Monoisotopic Mass 183.951781 g/mol

Nickel(II) Formate Dihydrate Health & Safety Information

Signal Word Danger
Hazard Statements H317-H334-H341-H350-H360-H372
Hazard Codes Xn
Precautionary Statements P201-P202-P260-P264-P270-P272-P280-P281-P285-P302+P352-P304+P341-P308+P313-P333+P313-P342+P311-P363-P501
Risk Codes N/A
Safety Statements N/A
Transport Information UN 3077 9/PG III
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/29/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Nickel(II) Formate Dihydrate

Product Number: All applicable American Elements product codes, e.g. NI2-FMAT-01-P.2HYD

CAS #: 15694-70-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements

Health Hazard - GHS08

Signal Word
Danger
Hazard Statements
May cause an allergic skin reaction
May cause allergy or asthma symptoms or breathing difficulties if inhaled
Suspected of causing genetic defects
May cause cancer
May damage fertility or the unborn child
Causes damage to organs through prolonged or repeated exposure
Precautionary Statements
Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
In case of inadequate ventilation wear respiratory protection
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Response
IF exposed or concerned: Get medical attention/advice
Inhalation
IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
Storage
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Very toxic to aquatic life with long lasting effects


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Nickel(II) formate dihydrate
Cas No.: 15694-70-9


SECTION 4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes.
Inhalation Move to fresh air.
Ingestion Do not induce vomiting.
Most important symptoms and
effects
May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause
allergic skin reaction. Breathing difficulties. Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness,
lightheadedness, chest pain, muscle pain or flushing: Symptoms of overexposure may be
headache, dizziness, tiredness, nausea and vomiting
Notes to Physician Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Unsuitable Extinguishing Media No information available
Flash Point Not applicable
Method - No information available
Autoignition Temperature Not applicable
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous Combustion Products
Carbon monoxide (CO) Carbon dioxide (CO2) Metal fumes and oxides
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment.
Environmental Precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained.
Methods for Containment and Clean Up
No information available.


SECTION 7. HANDLING AND STORAGE

Handling Ensure adequate ventilation.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Engineering Measures Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN 166
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Powder Solid
Appearance Green
Odor No information available
Odor Threshold No information available
pH Not applicable
Melting Point/Range 130 - 140 °C / 266 - 284 °F
Boiling Point/Range No information available
Flash Point Not applicable
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature Not applicable
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula Ni(HCO2)2•2H2O
Molecular Weight 184.77


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products.
Incompatible Materials Oxidizing agents
Hazardous Decomposition ProductsCarbon monoxide (CO), Carbon dioxide (CO2), Metal fumes and oxides
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure None known
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and delayed
Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing:
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment.
Persistence and Degradability Soluble in water Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name Nickel(II) formate dihydrate
Hazard Class 9
Packing Group III
TDG
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
IATA
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
IMDG/IMO
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III


SECTION 15. REGULATORY INFORMATION

U.S. Federal Regulations
TSCA 12(b) Not applicable
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA Occupational Safety and Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Nickel(II) Formate Dihydrate

Nickel(II) Formate Dihydrate is one of numerous organometallic compounds sold by American Elements under the trade name AE Organometallics™. Organometallics are useful reagent, catalyst, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others. American Elements supplies Nickel(II) Formate Dihydrate in most volumes including bulk quantities and also can produce materials to customer specifications. Please request a quote above for more information on pricing and lead time.

Nickel(II) Formate Dihydrate Synonyms

Nickel formate, Formic Acid nickel(2+) salt, nickel diformate dihydrate

Chemical Identifiers

Linear Formula Ni(HCO2)2•2H2O
MDL Number MFCD00153034
EC No. 222-101-0
Pubchem CID 12598460
IUPAC Name nickel(2+); diformate; dihydrate
SMILES C(=O)[O-].C(=O)[O-].O.O.[Ni+2]
InchI Identifier InChI=1S/2CH2O2.Ni.2H2O/c2*2-1-3;;;/h2*1H,(H,2,3);;2*1H2/q;;+2;;/p-2
InchI Key SMAMDWMLHWVJQM-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

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