20th anniversary seal20th anniversary seal20th anniversary seal

Nickel Sulfate Solution

CAS #:

Linear Formula:

NiSO4·6H2O

MDL Number:

MFCD00149813

EC No.:

232-104-9

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Nickel Sulfate Solution
NI-SAT-02-SOL
Pricing > SDS > Data Sheet >
(3N) 99.9% Nickel Sulfate Solution
NI-SAT-03-SOL
Pricing > SDS > Data Sheet >
(4N) 99.99% Nickel Sulfate Solution
NI-SAT-04-SOL
Pricing > SDS > Data Sheet >
(5N) 99.999% Nickel Sulfate Solution
NI-SAT-05-SOL
Pricing > SDS > Data Sheet >

Nickel Sulfate Solution Properties (Theoretical)

Compound Formula H12NiO10S
Molecular Weight 262.89
Appearance Liquid
Melting Point 53 °C
Boiling Point 100 °C (212 °F)
Density 2.07 g/cm3
Solubility in H2O N/A
Exact Mass 261.95046
Monoisotopic Mass 261.95047 Da

Nickel Sulfate Solution Health & Safety Information

Signal Word Danger
Hazard Statements H302-H315-H317-H332-H334-H341-H350i-H360D-H372-H410
Hazard Codes T, N
Risk Codes 49-61-20/22-38-42/43-48/23-50/53-68
Safety Statements 53-45-60-61
RTECS Number QR9600000
Transport Information UN 3288 6.1/PG 3
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 05/22/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Nickel Sulfate Solution

Product Number: All applicable American Elements product codes, e.g. NI-SAT-02-SOL , NI-SAT-03-SOL , NI-SAT-04-SOL , NI-SAT-05-SOL

CAS #: 10101-97-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1A H350 May cause cancer.
Repr. 1B H360 May damage fertility or the unborn child.
STOT RE 1 H372 Causes damage to the lung, the kidneys, the liver, the heart, the blood and the endocrine system through prolonged or repeated exposure.
Route of exposure: Oral, Inhalative.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Hazards not otherwise classified No data available.
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)

Health Hazard - GHS08Exclamation Mark - GHS07

Hazard pictograms
GHS08
Signal word Danger
Hazard-determining components of labeling:
Nickel(II) sulfate hexahydrate
Hazard statements
H315 Causes skin irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H372 Causes damage to the lung, the kidneys, the liver, the heart, the blood and the endocrine system through prolonged or repeated exposure. Route of exposure:
Oral, Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P284 In case of inadequate ventilation wear respiratory protection.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
2

1
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Mixtures
Dangerous components:
10101-97-0 Nickel(II) sulfate hexahydrate
Resp. Sens. 1, H334; Muta. 2, H341; Carc. 1A, H350; Repr. 1B, H360; STOT RE 1, H372; Acute Tox. 4, H302; Acute Tox. 4, H332;
Skin Irrit. 2, H315; Skin Sens. 1, H317
13.1%
Additional information None known.
Non-Hazardous Ingredients
7732-18-5 Water 86.9%


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact: Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed: Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed No information available.
Indication of any immediate medical attention and special treatment needed No information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Sulfur oxides (SOx)
Toxic metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without official permits.
Methods and material for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Ensure adequate ventilation.
Open and handle container with care.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: Refrigerate
Information about storage in one common storage facility:
Protect from heat.
Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many reactive organic and inorganic chemicals.
Further information about storage conditions:
Keep container tightly sealed.
Refrigerate
Specific end use(s) No information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
10101-97-0 Nickel(II) sulfate hexahydrate (13.1%)
PEL (USA) Long-term value: 1 mg/m³
as Ni
REL (USA) Long-term value: 0.015 mg/m³
as Ni; See Pocket Guide App. A
TLV (USA) Long-term value: 0.1 mg/m³
as Ni; inhalable fraction
EV (Canada) Long-term value: 0.1 mg/m³
Inhalable fraction, as Ni
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical general protective and industrial hygiene measures for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes) No data available.
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Liquid
Color: Green
Odor: Odorless
Odor threshold: No data available.
pH: No data available.
Melting point/range: No data available.
Boiling point/range: No data available.
Sublimation temperature / start: No data available.
Flammability (solid, gas): No data available.
Ignition temperature: No data available.
Decomposition temperature: No data available.
Auto igniting: Product is not selfigniting.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure at 20 °C (68 °F): 23 hPa (17 mm Hg)
Density: No data available.
Relative density No data available.
Vapor density No data available.
Evaporation rate No data available.
Solubility in / Miscibility with
Water: Fully miscible
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Solvent content:
Organic solvents: 0.0 %
Solids content: 13.1 %
Other information No information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Water reacts violently with alkali metals.
Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many reactive organic and inorganic chemicals.
Conditions to avoid No information available.
Incompatible materials: Heat
Hazardous decomposition products:
Sulfur oxides (SOx)
Toxic metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: N/A
LD/LC50 values that are relevant for classification:
10101-97-0 Nickel(II) sulfate hexahydrate
Oral LD50 264 mg/kg (rat)
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization:
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Germ cell mutagenicity: Suspected of causing genetic defects.
Carcinogenicity:
May cause cancer.
IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.
ACGIH A1: Confirmed human carcinogen: Agent is carcinogenic to humans based on epidemiologic studies of, or convincing clinical evidence in, exposed humans.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
Reproductive toxicity: May damage fertility or the unborn child.
Specific target organ system toxicity - repeated exposure:
Causes damage to the lung, the kidneys, the liver, the heart, the blood and the endocrine system through prolonged or repeated exposure. Route of exposure: Oral,
Inhalative.
Specific target organ system toxicity - single exposure: N/A
Aspiration hazard: N/A
Subacute to chronic toxicity: N/A
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic if inhaled.
May cause harm to the unborn child


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No information available.
Persistence and degradability: No information available.
Bioaccumulative potential: No information available.
Mobility in soil: No information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without official permits.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A.
Other adverse effects No information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation: Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN3082
UN proper shipping name
DOT Environmentally hazardous substances, liquid, n.o.s. (Nickel(II) sulfate
hexahydrate)
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Nickel(II)
sulfate hexahydrate), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Nickel(II)
sulfate hexahydrate)
Transport hazard class(es)
DOT
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Class 9 (M6) Miscellaneous dangerous substances and articles
Label 9
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant (IMDG): Symbol (fish and tree)
Special marking (ADR): Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN3082, Environmentally hazardous substances, liquid, n.o.s. (Nickel(II) sulfate
hexahydrate), 9, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS08
Signal word Danger
Hazard-determining components of labeling:
Nickel(II) sulfate hexahydrate
Hazard statements
H315 Causes skin irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H372 Causes damage to the lung, the kidneys, the liver, the heart, the blood and the endocrine system through prolonged or repeated exposure. Route of exposure:
Oral, Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P284 In case of inadequate ventilation wear respiratory protection.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
10101-97-0 Nickel(II) sulfate hexahydrate 13.1%
California Proposition 65
Prop 65 - Chemicals known to cause cancer
10101-97-0 Nickel(II) sulfate hexahydrate 13.1%
Prop 65 - Developmental toxicity
None of the ingredients are listed.
Prop 65 - Developmental toxicity, female
None of the ingredients are listed.
Prop 65 - Developmental toxicity, male
None of the ingredients are listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
None of the ingredients are listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
None of the ingredients is listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
None of the ingredients is listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Nickel Sulfate Solution

Sulfate IonNickel Sulfate Solutions are moderate to highly concentrated liquid solutions of Nickel Sulfate. They are an excellent source of Nickel Sulfate for applications requiring solubilized Compound Solutions Packaging, Bulk Quantity materials. American Elements can prepare dissolved homogeneous solutions at customer specified concentrations or to the maximum stoichiometric concentration. Packaging is available in 55 gallon drums, smaller units and larger liquid totes. American Elements maintains solution production facilities in the United States, Northern Europe (Liverpool, UK), Southern Europe (Milan, Italy), Australia and China to allow for lower freight costs and quicker delivery to our customers. American Elements metal and rare earth compound solutions have numerous applications, but are commonly used in petrochemical cracking and automotive catalysts, water treatment, plating, textiles, research and in optic, laser, crystal and glass applications. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Nickel Sulfate Powder. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles and deposited utilizing sputtering targets and evaporation materials for uses such as solar cells and fuel cells. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Nickel Sulfate Solution Synonyms

Nickel(II) sulfate, Nickel(II) sulfate hexahydrate

Chemical Identifiers

Linear Formula NiSO4·6H2O
MDL Number MFCD00149813
EC No. 232-104-9
Beilstein Registry No. N/A
Pubchem CID 5284429
IUPAC Name nickel(2+) sulfate hexahydrate
SMILES [Ni+2].[O-]S([O-])(=O)=O.O.O.O.O.O.O
InchI Identifier InChI=1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2
InchI Key RRIWRJBSCGCBID-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

TODAY'S SCIENCE POST!

May 22, 2019
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day

Drone uses swiveling propellor arms to become a robotic car when it hits the ground