Nitrogen-doped carbon quantum dots/Ag3PO4 complex photocatalysts with enhanced visible light driven photocatalytic activity and stability.

Title Nitrogen-doped carbon quantum dots/Ag3PO4 complex photocatalysts with enhanced visible light driven photocatalytic activity and stability.
Authors Q. Chen; Y. Wang; Y. Wang; X. Zhang; D. Duan; C. Fan
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2016.12.013
Abstract

Novel nitrogen-doped carbon quantum dots/Ag3PO4 (NCQDs/Ag3PO4) complex photocatalysts were synthesized by a facile precipitation method at room temperature. The physical and chemical properties of Ag3PO4 and NCQDs/Ag3PO4 photocatalysts were detected through X-ray powder diffraction, field emission scanning electron microscopy, UV-vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy and electron spin resonance techniques. The as-prepared 3-NCQDs/Ag3PO4 composite exhibited much higher activity than the pure Ag3PO4 for eliminating methyl orange and bisphenol A solution under visible light (?>420nm). Moreover, in the cyclic experiments, the 3-NCQDs/Ag3PO4 exhibited an excellent stability for the decolorization of methyl orange at some level. This suggested that NCQDs played an important role in the process of degradation. The function of NCQDs was discussed and a new mechanism was put forward for the degradation of methyl orange. The high activities and stability were attributed to the transfer of photogenerated charges through the vector of Ag3PO4?NCQDs?Ag in the photocatalytic process, leading to effective charge separation of Ag3PO4.

Citation Q. Chen; Y. Wang; Y. Wang; X. Zhang; D. Duan; C. Fan.Nitrogen-doped carbon quantum dots/Ag3PO4 complex photocatalysts with enhanced visible light driven photocatalytic activity and stability.. J Colloid Interface Sci. 2017;491:238245. doi:10.1016/j.jcis.2016.12.013

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Carbon

See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

Phosphorus

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Silver

See more Silver products. Silver (atomic symbol: Ag, atomic number: 47) is a Block D, Group 11, Period 5 element with an atomic weight of 107.8682. Silver Bohr ModelThe number of electrons in each of Silver's shells is 2, 8, 18, 18, 1 and its electron configuration is [Kr]4d10 5s1. The silver atom has a radius of 144 pm and a Van der Waals radius of 203 pm. Silver was first discovered by Early Man prior to 5000 BC. In its elemental form, silver has a brilliant white metallic luster. Elemental SilverIt is a little harder than gold and is very ductile and malleable, being exceeded only by gold and perhaps palladium. Pure silver has the highest electrical and thermal conductivity of all metals and possesses the lowest contact resistance. It is stable in pure air and water, but tarnishes when exposed to ozone, hydrogen sulfide, or air containing sulfur. It is found in copper, copper-nickel, lead, and lead-zinc ores, among others. Silver was named after the Anglo-Saxon word "seolfor" or "siolfur," meaning 'silver'.

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