Pb2BO3I: A New Borate Iodide with the Largest SHG Response in the KBe2BO3F2 (KBBF) Family.

Title Pb2BO3I: A New Borate Iodide with the Largest SHG Response in the KBe2BO3F2 (KBBF) Family.
Authors H. Yu; N. Koocher; J. Rondinelli; S. Halasyamani
Journal Angew Chem Int Ed Engl
DOI 10.1002/anie.201802079
Abstract

Borate halides are an ideal materials class from which to design high-performance nonlinear optical (NLO) materials. Currently, borate fluorides, chlorides, and bromides are extensively investigated while borate iodide materials discovery remains rare due to perceived synthetic challenges. We report a new borate iodide, Pb2BO3I synthesized by a straightforward hydrothermal method. The Pb2BO3I chemical formula conceals that the compound exhibits a structure similiar to the well-known KBe2BO3F2 (KBBF), which we show supports the highest second-harmonic generation (SHG) at 1064 nm in the KBBF family, 10 x KH2PO4 (KDP), arising from the inclusion of Pb2+ and I- and the aforementioned crystal-chemistry. Our work shows that KBBF-related compounds can be synthesized in iodide chemistries to exhibit superior NLO reponses.

Citation H. Yu; N. Koocher; J. Rondinelli; S. Halasyamani.Pb2BO3I: A New Borate Iodide with the Largest SHG Response in the KBe2BO3F2 (KBBF) Family.. Angew Chem Int Ed Engl. 2018. doi:10.1002/anie.201802079

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