Phase controlled synthesis of nickel phosphide nanocrystals and their electro-catalytic performance for hydrogen evolution reaction.

Title Phase controlled synthesis of nickel phosphide nanocrystals and their electro-catalytic performance for hydrogen evolution reaction.
Authors H. Li; S. Lu; J. Sun; J. Pei; D. Liu; Y. Xue; J. Mao; W. Zhu; Z. Zhuang
Journal Chemistry
DOI 10.1002/chem.201801964
Abstract

Phase of the nanocrystals acts as a key role in the modulation of catalytic properties. Uniform and well-crystallized nickel phosphide nanocrystals with controlled phases (Ni5P4, Ni2P and Ni12P5) and narrow size distributions are synthesized by a wet chemical method. The phases of the as-synthesized nickel phosphide nanocrystals are controlled by the P/Ni precursor molar ratio, heating process and time of reaction. The rarely reported nearly monodisperse 5.6 nm Ni5P4 nanocrystals are successfully synthesized and show superior hydrogen evolution reaction (HER) activity. It only needs a low overpotential of 103 mV to achieve the HER current of 10 mA cm-2 at a low catalyst loading of 0.12 mg cm-2. The high HER activity is attributed to the high quality of the as-obtained Ni5P4 nanocrystals, which have the electronic effect from the Ni5P4 phase and also high surface area by the small particle size. A systematic study on the controlled synthesis of nickel phosphide nanocrystals is shown in this paper, and the HER catalytic activity is improved through the phase- and size-controlled synthesis of nanocrystals.

Citation H. Li; S. Lu; J. Sun; J. Pei; D. Liu; Y. Xue; J. Mao; W. Zhu; Z. Zhuang.Phase controlled synthesis of nickel phosphide nanocrystals and their electro-catalytic performance for hydrogen evolution reaction.. Chemistry. 2018. doi:10.1002/chem.201801964

Related Elements

Phosphorus

Phosphorus Bohr ModelSee more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

Nickel

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