Phenolic sensor development based on chromium oxide-decorated carbon nanotubes for environmental safety.

Title Phenolic sensor development based on chromium oxide-decorated carbon nanotubes for environmental safety.
Authors M.M. Rahman; H.B. Balkhoyor; A.M. Asiri
Journal J Environ Manage
DOI 10.1016/j.jenvman.2016.12.008
Abstract

A nanocomposite (NC) composed of chromium(III)oxide nanomaterials decorated carbon nanotubes (Cr2O3-CNT NC) was prepared via a simple solution method with reducing agents in an alkaline medium. The Cr2O3-CNT NC was characterized using ultraviolet-visible (UV/Vs.) spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, energy-dispersive X-ray spectroscopy (XEDS), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and field-emission scanning electron microscopy (FESEM). The Cr2O3-CNT composite was deposited on a flat glassy carbon electrode (GCE) with conducting nafion (5%) binders to produce a sensor that exhibited fast response and high selectivity toward 4-methoxyphenol (4MP) in phosphate buffer phase at pH 7. Furthermore, the sensor performance parameters, including the sensitivity, lower detection range, reliability, and reproducibility, ease of integration, long-term stability, and selectivity were investigated in detail. The calibration plot was found to be linear in the concentration range of 0.01 nM-0.1 ?M. The sensitivity and detection limit were calculated as 1.4768 ?A cm(-2) ?M(-1) and 0.06428 ± 0.0002 nM (at a signal-to-noise ratio of 3), respectively. Thus, it was concluded that the proposed selective and efficient sensor represents a promising approach to effectively detect toxic phenolic compounds in the environment with acceptable and reliable results.

Citation M.M. Rahman; H.B. Balkhoyor; A.M. Asiri.Phenolic sensor development based on chromium oxide-decorated carbon nanotubes for environmental safety.. J Environ Manage. 2017;188:228237. doi:10.1016/j.jenvman.2016.12.008

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