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Platinum Ink

Pt

MDL Number:

MFCD00011179

EC No.:

231-116-1

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PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
Platinum Ink
PT-M-01-INK
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Platinum Ink Properties

Molecular Weight

195.08

Appearance

Gray paste

Melting Point

380 °C

Boiling Point

N/A

Density

N/A

Solubility in H2O

Not miscible or difficult to mix

Tensile Strength

N/A

Thermal Conductivity

0.716 W/cm/K

Electrical Resistivity

10.6 µÎ©-cm (20 °C)

Electronegativity

2.2 Paulings

Specific Heat

0.0317 Cal/g/K @ 25 °C

Heat of Vaporization

122 K-Cal/gm atom at 3827 °C

Platinum Ink Health & Safety Information

Signal Word Danger
Hazard Statements H360-H226-H315-H333
Hazard Codes F, Xi
Precautionary Statements P210-P201-P280-P281-P240-P241-P303+P361+P353-P362-P405-P501a
Risk Codes N/A
Safety Statements N/A
Transport Information UN1263 3/PG III
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Created: 5/15/2015
Date Revised: 5/15/2015

SECTION 1. IDENTIFICATION

Product Name: Platinum Ink

Product Number: All applicable American Elements product codes, e.g. PT-M-01-INK

Relevant identified uses of the substance: Scientific research and development


SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 health hazard
Repr. 1B H360FD May damage fertility. May damage the unborn child.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Other hazards that do not result in classification No information known.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation.
Hazard pictograms

Flame - GHS02 Exclamation Mark - GHS07 Health Hazard - GHS08

GHS02 GHS07 GHS08
Signal word Danger
Hazard-determining components of labelling:
2-Ethoxyethyl acetate
Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H360FD May damage fertility. May damage the unborn child.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Dangerous components:
CAS: 98-55-5
EINECS: 202-680-6
alpha-Terpineol
Skin Irrit. 2, H315
7,0%
CAS: 111-15-9
EINECS: 203-839-2
Index number: 607-037-00-7
2-Ethoxyethyl acetate
Flam. Liq. 3, H226; Repr. 1B, H360FD; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332
7,0%
CAS: 9004-70-0
EC number: 618-392-2
Nitrocellulose
Flam. Sol. 1, H228; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
7,0%
Additional information None known.
Non-Hazardous Ingredients
CAS: 7440-06-4
EINECS: 231-116-1
Platinum


SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
5.2 Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Platinum oxide
5.3 Advice for firefighters
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: Keep away from ignition sources.
6.4 Reference to other sections
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.


SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers: No special requirements.
Information about storage in one common storage facility: Store away from oxidising agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Store in a locked cabinet or with access restricted to technical experts or their assistants.
7.3 Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
8.1 Control parameters
Components with critical values that require monitoring at the workplace:
7440-06-4 Platinum (79,0%)
AGW (Germany) Long-term value: 1 E mg/m³
EU, 13
PEL (USA) Long-term value: 0,002 mg/m³
soluble salts, as Pt
REL (USA) Long-term value: 1* 0,002** mg/m³
*Metal **soluble salts, as Pt
TLV (USA) Long-term value: 1* 0,002** mg/m³
*metal **soluble salts, as Pt
111-15-9 2-Ethoxyethyl acetate (7,0%)
AGW (Germany) Long-term value: 10,8 mg/m³, 2 ppm
8(II);EU, DFG, H, Z
PEL (USA) Long-term value: 540 mg/m³, 100 ppm
Skin
REL (USA) Long-term value: 2,7 mg/m³, 0,5 ppm
Skin
TLV (USA) Long-term value: 27 mg/m³, 5 ppm
Skin; BEI
Ingredients with biological limit values:
111-15-9 2-Ethoxyethyl acetate (7,0%)
BGW (Germany) 50 mg/l
Untersuchungsmaterial: Urin
Probennahmezeitpunkt: bei Langzeitexposition: Nach mehreren vorangegangenen Schichten
Parameter: Ethoxyessigsäure
BEI (USA) 100 mg/g creatinine
Medium: urine
Time: end of shift at end of workweek
Parameter: 2-Ethoxyacetic acid
Additional information: No data
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Store protective clothing separately.
Do not inhale dust / smoke / mist.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use breathing protection with high concentrations.
Recommended filter device for short term use:
Use a respirator with multi-purpose combination (US) or type ABEK (EN 14387) as a backup to engineering controls. Risk assessment should be performed to
determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards such as NIOSH (USA)
or CEN (EU).
Protection of hands:
Check protective gloves prior to each use for their proper condition.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Material of gloves Impervious gloves
Eye protection:
Safety glasses
Face protection
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Paste
Smell: Not determined
Odour threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Inflammability (solid, gaseous) Not determined.
Ignition temperature: 380 °C
Decomposition temperature: Not determined
Self-inflammability: Product is not selfigniting.
Danger of explosion: Not determined.
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density Not determined
Relative density Not determined.
Vapour density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not determined.
kinematic: Not determined.
Solvent content:
Organic solvents: 7,0 %
Solids content: 86,0 %
9.2 Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity No information known.
10.2 Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications.
10.3 Possibility of hazardous reactions Reacts with strong oxidising agents
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: Oxidising agents
10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Platinum oxide


SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
98-55-5 alpha-Terpineol
Oral LD50 3200 mg/kg (RAT)
111-15-9 2-Ethoxyethyl acetate
Oral LD50 2700 mg/kg (rat)
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effect known.
Germ cell mutagenicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for components in this product.
Carcinogenicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carcinogenic and/or neoplastic data for components in this product.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for components in this product.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the
latest version:
Product is suspected to cause injury to foetus.
May cause harm to the unborn child.


SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Recommendation
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Consult state, local or national regulations for proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
ADR, IMDG, IATA UN1263
14.2 UN proper shipping name
ADR 1263 PAINT, special provision 640E
IMDG, IATA PAINT
14.3 Transport hazard class(es)
ADR
Class 3 (F1) Flammable liquids.
Label 3
IMDG, IATA
Class 3 Flammable liquids.
Label 3
Packing group
ADR, IMDG, IATA III
14.5 Environmental hazards:
Marine pollutant: No
14.6 Special precautions for user Warning: Flammable liquids.
Kemler Number: 30
EMS Number: F-E,S-E
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC
Code Not applicable.
Transport/Additional information:
ADR
Excepted quantities (EQ): E1
Limited quantities (LQ) 5L
Transport category 3
Tunnel restriction code D/E
UN "Model Regulation": UN1263, PAINT, special provision 640E, 3, III


SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Inventory of Chemical Substances
All ingredients are listed.
Standard for the Uniform Scheduling of Medicines and Poisons
None of the ingredients is listed.
National regulations
Information about limitation of use:
Employment restrictions concerning young persons must be observed.
Employment restrictions concerning women of child-bearing age must be observed.
For use only by technically qualified individuals.
Classification according to VbF: Not applicable
Technical instructions (air):
Class Share in %
NK 7,0
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
Other regulations, limitations and prohibitive regulations
ELINCS (European List of Notified Chemical Substances)
None of the ingredients is listed.
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
111-15-9 2-Ethoxyethyl acetate
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on
the market and use must be observed.
None of the ingredients is listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
None of the ingredients is listed.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Platinum Ink

Platinum Ink is a screen-printable electrode material for ceramic substrates in solid oxide fuel cells (SOFCs), sensors, and other applications. Platinum ink is generally immediately available in most volumes, including bulk orders. American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as numerous other machined shapes and in the form of solutions and organometallic compounds. Ultra high purity and high purity forms also include metal powder, submicron powder and nanomaterials, targets for thin film deposition, and pellets for chemical vapor deposition (CVD) and physical vapor deposition (PVD) applications. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available, as is additional research, technical and safety (MSDS) data. Please contact us for information on lead time and pricing above.

Platinum Ink Synonyms

N/A

Platinum Ink Chemical Identifiers

Linear Formula

Pt

Pubchem CID

23939

MDL Number

MFCD00011179

EC No.

231-116-1

Beilstein Registry No.

N/A

SMILES

[Pt]

InchI Identifier

InChI=1S/Pt

InchI Key

BASFCYQUMIYNBI-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Platinum products. Platinum (atomic symbol: Pt, atomic number: 78) is a Block D, Group 10, Period 6 element with an atomic weight of 195.084. The number of electrons in each of platinum's shells is [2, 8, 18, 32, 17, 1] and its electron configuration is [Xe] 4f14 5d9 6s1. The platinum atom has a radius of 139 pm and a Van der Waals radius of 175 pm. Platinum Bohr ModelElemental PlatinumPlatinum was discovered and first isolated by Antonio de Ulloa in 1735. It is one of the rarest elements in the earth's crust, occurring at a concentration of only 0.005 ppm. Platinum is found uncombined as a free element and alloyed with iridium as platiniridium. In its elemental form, platinum has a grayish white appearance. It is highly resistant to corrosion: the metal does not oxidize in air at any temperature. It is generally non-reactive, even at high temperatures. The origin of the name "platinum" comes from the Spanish word platina, meaning silver.

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