Polyaniline Derived N-Doped Carbon-Coated Cobalt Phosphide Nanoparticles Deposited on N-Doped Graphene as an Efficient Electrocatalyst for Hydrogen Evolution Reaction.

Title Polyaniline Derived N-Doped Carbon-Coated Cobalt Phosphide Nanoparticles Deposited on N-Doped Graphene as an Efficient Electrocatalyst for Hydrogen Evolution Reaction.
Authors J. Ma; M. Wang; G. Lei; G. Zhang; F. Zhang; W. Peng; X. Fan; Y. Li
Journal Small
DOI 10.1002/smll.201702895
Abstract

The development of highly efficient and durable non-noble metal electrocatalysts for the hydrogen evolution reaction (HER) is significant for clean and renewable energy research. This work reports the synthesis of N-doped graphene nanosheets supported N-doped carbon coated cobalt phosphide (CoP) nanoparticles via a pyrolysis and a subsequent phosphating process by using polyaniline. The obtained electrocatalyst exhibits excellent electrochemical activity for HER with a small overpotential of -135 mV at 10 mA cm-2 and a low Tafel slope of 59.3 mV dec-1 in 0.5 m H2 SO4 . Additionally, the encapsulation of N-doped carbon shell prevents CoP nanoparticles from corrosion, exhibiting good stability after 14 h operation. Moreover, the as-prepared electrocatalyst also shows outstanding activity and stability in basic and neutral electrolytes.

Citation J. Ma; M. Wang; G. Lei; G. Zhang; F. Zhang; W. Peng; X. Fan; Y. Li.Polyaniline Derived N-Doped Carbon-Coated Cobalt Phosphide Nanoparticles Deposited on N-Doped Graphene as an Efficient Electrocatalyst for Hydrogen Evolution Reaction.. Small. 2017. doi:10.1002/smll.201702895

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Cobalt

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