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Potassium Hydroxide Solution

CAS #:

Linear Formula:

KOH

MDL Number:

MFCD00003553

EC No.:

215-181-3

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Potassium Hydroxide Solution
K-OH-02-SOL
Pricing > SDS > Data Sheet >
(3N) 99.9% Potassium Hydroxide Solution
K-OH-03-SOL
Pricing > SDS > Data Sheet >
(4N) 99.99% Potassium Hydroxide Solution
K-OH-04-SOL
Pricing > SDS > Data Sheet >
(5N) 99.999% Potassium Hydroxide Solution
K-OH-05-SOL
Pricing > SDS > Data Sheet >
Question? Ask an American Elements EngineerWHOLESALE/SKU 0000-742-13064

Potassium Hydroxide Solution Properties

Compound Formula

HKO

Molecular Weight

56.11

Appearance

Colorless Liquid

Melting Point

N/A

Boiling Point

N/A

Density (Theoretical)

N/A

Monoisotopic Mass

N/A

Charge

N/A

Potassium Hydroxide Solution Health & Safety Information

Signal Word Danger
Hazard Statements H302-H314
Hazard Codes C
Risk Codes 22-35
Safety Statements 26-36/37/39-45
RTECS Number TT2100000
Transport Information UN 1813 8/PG 2
WGK Germany 1
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/24/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Potassium Hydroxide Solution

Product Number: All applicable American Elements product codes, e.g. K-OH-02-SOL , K-OH-03-SOL , K-OH-04-SOL , K-OH-05-SOL

CAS #: 1310-58-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Hazards not otherwise classified No information known.
Label elements
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Exclamation Mark - GHS07 Corrosion - GHS05

GHS05 GHS07
Signal word Danger
Hazard-determining components of labeling:
Potassium hydroxide
Hazard statements
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
E - Corrosive material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
3

2
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Mixtures
Dangerous components:
1310-58-3 Potassium hydroxide Skin Corr. 1A, H314; Acute Tox. 4, H302 45.0%
Additional information None known.
Non-Hazardous Ingredients
7732-18-5 Water 55.0%


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information Immediately remove any clothing soiled by the product.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Potassium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Use neutralizing agent.
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from halogens.
Store away from halocarbons.
Store away from alcohols.
Store away from acid chlorides.
Store away from acid anhydrides.
Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many reactive organic and inorganic chemicals.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
1310-58-3 Potassium hydroxide (45.0%)
REL (USA) Ceiling limit value: 2 mg/m³
TLV (USA) Ceiling limit value: 2 mg/m³
EL (Canada) Short-term value: C 2 mg/m³
AAdditional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes) Not determined
Eye protection:
Tightly sealed goggles
Full face protection
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Colorless
Odor: Not determined
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous) Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Product is not selfigniting.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure at 20 °C (68 °F): 23 hPa (17 mm Hg)
Density: Not determined
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not determined.
kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
Solids content: 45.0 %
Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity No information known.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with acids
Water reacts violently with alkali metals.
Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many reactive organic and inorganic chemicals.
Conditions to avoid No further relevant information available.
Incompatible materials:
Acids
Halogens
Halocarbons
Alcohols
Acid chlorides
Acid anhydrides
Hazardous decomposition products: Potassium oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful if swallowed.
Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach.
The following RTECS statement/statements refer to the anhydrous compound:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
1310-58-3 Potassium hydroxide
Oral LD50 273 mg/kg (rat)
Skin irritation or corrosion: Causes severe skin burns.
Eye irritation or corrosion: Causes serious eye damage.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity:
The following RTECS statement/statements refer to the anhydrous compound:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for components in this product.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN1814
UN proper shipping name
DOT Potassium hydroxide, solution
IMDG, IATA POTASSIUM HYDROXIDE SOLUTION
Transport hazard class(es)
DOT
Class 8 Corrosive substances.
Label 8
Class 8 (C5) Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances.
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant (IMDG): No
Special precautions for user Warning: Corrosive substances
EMS Number: F-A,S-B
Segregation groups Alkalis
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN1814, Potassium hydroxide, solution, 8, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard-determining components of labeling:
Potassium hydroxide
Hazard statements
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
None of the ingredients are listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
None of the ingredients are listed.
Prop 65 - Developmental toxicity
None of the ingredients are listed.
Prop 65 - Developmental toxicity, female
None of the ingredients are listed.
Prop 65 - Developmental toxicity, male
None of the ingredients are listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
None of the ingredients are listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
None of the ingredients is listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
None of the ingredients is listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Potassium Hydroxide Solution

Potassium Hydroxide Solution is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Potassium Hydroxide Solution Synonyms

Aqueous potassium hydroxide

Potassium Hydroxide Solution Chemical Identifiers

Linear Formula

KOH

Pubchem CID

14797

MDL Number

MFCD00003553

EC No.

215-181-3

Beilstein Registry No.

N/A

IUPAC Name

potassium hydroxide

SMILES

[K+].[OH-]

InchI Identifier

InChI=1S/K.H2O/h;1H2/q+1;/p-1

InchI Key

KWYUFKZDYYNOTN-UHFFFAOYSA-M

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Elemental PotassiumSee more Potassium products. Potassium (atomic symbol: K, atomic number: 19) is a Block S, Group 1, Period 4 element with an atomic weight of 39.0983. The number of electrons in each of Potassium's shells is [2, 8, 8, 1] and its electron configuration is [Ar] 4s1. The potassium atom has a radius of 227.2 pm and a Van der Waals radius of 275 pm. Potassium was discovered and first isolated by Sir Humphrey Davy in 1807. Potassium is the seventh most abundant element on earth. It is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other alkali metals, potassium decomposes in water with the evolution of hydrogen because of its reacts violently with water, it only occurs in nature in ionic salts.Potassium Bohr Model In its elemental form, potassium has a silvery gray metallic appearance, but its compounds (such as potassium hydroxide) are more frequently used in industrial and chemical applications. The origin of the element's name comes from the English word 'potash,' meaning pot ashes, and the Arabic word qali, which means alkali. The symbol K originates from the Latin word kalium.

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November 24, 2017
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