Rapid synthesis of platinum-ruthenium bimetallic nanoparticles dispersed on carbon support as improved electrocatalysts for ethanol oxidation.

Title Rapid synthesis of platinum-ruthenium bimetallic nanoparticles dispersed on carbon support as improved electrocatalysts for ethanol oxidation.
Authors Z. Gu; S. Li; Z. Xiong; H. Xu; F. Gao; Y. Du
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2018.03.035
Abstract

Bimetallic nanocatalysts with small particle size benefit from markedly enhanced electrocatalytic activity and stability during small molecule oxidation. Herein, we report a facile method to synthesize binary Pt-Ru nanoparticles dispersed on a carbon support at an optimum temperature. Because of its monodispersed nanostructure, synergistic effects were observed between Pt and Ru and the PtRu/C electrocatalysts showed remarkably enhanced electrocatalytic activity towards ethanol oxidation. The peak current density of the PtRu/C electrocatalyst is 3731?mA?mg, which is 9.3 times higher than that of commercial Pt/C (401?mA?mg). Furthermore, the synthesized PtRu/C catalyst exhibited higher stability during ethanol oxidation in an alkaline medium and maintained a significantly higher current density after successive cyclic voltammograms (CVs) of 500 cycles than commercial Pt/C. Our work highlights the significance of the reaction temperature during electrocatalyst synthesis, leading to enhanced catalytic performance towards ethanol oxidation. The PtRu/C electrocatalyst has great potential for application in direct ethanol fuel cells.

Citation Z. Gu; S. Li; Z. Xiong; H. Xu; F. Gao; Y. Du.Rapid synthesis of platinum-ruthenium bimetallic nanoparticles dispersed on carbon support as improved electrocatalysts for ethanol oxidation.. J Colloid Interface Sci. 2018;521:111118. doi:10.1016/j.jcis.2018.03.035

Related Elements

Platinum

See more Platinum products. Platinum (atomic symbol: Pt, atomic number: 78) is a Block D, Group 10, Period 6 element with an atomic weight of 195.084. The number of electrons in each of platinum's shells is [2, 8, 18, 32, 17, 1] and its electron configuration is [Xe] 4f14 5d9 6s1. The platinum atom has a radius of 139 pm and a Van der Waals radius of 175 pm. Platinum Bohr ModelElemental PlatinumPlatinum was discovered and first isolated by Antonio de Ulloa in 1735. It is one of the rarest elements in the earth's crust, occurring at a concentration of only 0.005 ppm. Platinum is found uncombined as a free element and alloyed with iridium as platiniridium. In its elemental form, platinum has a grayish white appearance. It is highly resistant to corrosion: the metal does not oxidize in air at any temperature. It is generally non-reactive, even at high temperatures. The origin of the name "platinum" comes from the Spanish word platina, meaning silver.

Ruthenium

See more Ruthenium products. Ruthenium (atomic symbol: Ru, atomic number: 44) is a Block D, Group 8, Period 5 element with an atomic weight of 101.07. Ruthenium Bohr ModelThe number of electrons in each of ruthenium's shells is [2, 8, 18, 15, 1] and its electron configuration is [Kr] 4d7 5s1. The ruthenium atom has a radius of 134 pm and a Van der Waals radius of 207 pm. Ruthenium was discovered by Jędrzej Śniadecki in 1807. It was first recognized as a distinct element by Karl Ernst Claus in 1844. Elemental RutheniumIn its elemental form, ruthenium has a silvery white metallic appearance. Ruthenium is a rare transition metal belonging to the platinum group of metals. It is found in pentlandite, pyroxenite, and platinum group metal ores. The name Ruthenium originates from the Latin word "Ruthenia," meaning Russia.

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