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A Scandium Metalloligand-Based Heterobimetallic Pd-Sc Complex: Electronic Tuning Through a Very Short Pd→Sc Dative Bond.

Author(s) Du, J.; Huang, Z.; Zhang, Y.; Wang, S.; Zhou, S.; Fang, H.; Cui, P.
Journal Chemistry
Date Published 2019 Aug 01
Abstract

The first heterobimetallic Pd-Sc complex featuring a very short Pd→Sc dative bond has been synthesized and characterized by multinuclear NMR spectroscopy, X-ray diffraction analysis, and electrochemistry. Computational studies elucidated the nature of the Pd→Sc bond as a donor-acceptor interaction, which generates a more electron-deficient Pd metal center as compared to that in the mono Pd complex in their reactions with isonitrile and carbon monoxide. Cooperative reactivity has been demonstrated in the reaction with MeI.

DOI 10.1002/chem.201901424
ISSN 1521-3765
Citation Du J, Huang Z, Zhang Y, Wang S, Zhou S, Fang H, et al. A Scandium Metalloligand-Based Heterobimetallic Pd-Sc Complex: Electronic Tuning Through a Very Short Pd→Sc Dative Bond. Chemistry. 2019;25(43):10149-10155.

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