A thermoelectric copper-iodide composite from the pyrolysis of a well-defined coordination polymer.

Author(s) Bai, S.Q.; Wong, I.Hoi Ka; Lin, M.; Young, D.James; Hor, T.S.Andy
Journal Dalton Trans
Date Published 2018 Apr 09
Abstract

Coordination polymer 1 was prepared from CuI and a flexible [SNS] ligand L in acetonitrile. The thermal decomposition of 1 yielded a CuI-rich thermoelectric carbon composite 2, which is relatively light, thermally stable and robust. Composite 2 possesses high Seebeck coefficients (700-950 μV K-1) from rt to 204 °C after an optimization cycle.

DOI 10.1039/c8dt00090e
ISSN 1477-9234
Citation Bai S-, Wong IH, Lin M, Young DJ, Hor TS. A thermoelectric copper-iodide composite from the pyrolysis of a well-defined coordination polymer. Dalton Trans. 2018.

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