Biosorption of praseodymium (III) using Terminalia arjuna bark powder in batch systems: isotherm and kinetic studies.

Author(s) Swain, K.Kumari; Mishra, P.Manjari; Devi, A.Prabha
Journal Water Sci Technol
Date Published 2018 Feb
Abstract

The high demand for rare earth elements (REEs) used in various advanced materials implies demand for increased production of REEs or the recycling of solutions to recover the REEs they contain. In this study, the biosorption of Pr(III) from aqueous solution by bark powder of Terminalia arjuna was examined in a batch system as a function of metal concentration, biosorbent dosage, pH and contact time. Results showed that T. arjuna bark powder has a high affinity for adsorbing Pr(III): more than 90% at pH 6.63. The adsorption of Pr(III) by T. arjuna bark powder was investigated by the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. The kinetics of the biosorption process was tested with pseudo-first-order and pseudo-second-order models, and the results showed that the biosorption process was better fitted to the pseudo-second-order model. From Fourier transform infrared spectroscopy (FT-IR) analysis, it is confirmed that the biomolecules of T. arjuna bark powder are involved in the biosorption process of Pr(III) metal ions.

DOI 10.2166/wst.2017.589
Keywords Adsorption; Hydrogen-Ion Concentration; Kinetics; Plant Bark; Praseodymium; Recycling; Spectroscopy, Fourier Transform Infrared; Terminalia; Waste Disposal, Fluid; Water Pollutants, Chemical
ISSN 0273-1223
Citation Swain KK, Mishra PM, Devi AP. Biosorption of praseodymium (III) using Terminalia arjuna bark powder in batch systems: isotherm and kinetic studies. Water Sci Technol. 2018;77(3-4):727-738.

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