Effects of Ca/Si Ratio, Aluminum and Magnesium on the Carbonation Behavior of Calcium Silicate Hydrate.

Author(s) Li, J.; Yu, Q.; Huang, H.; Yin, S.
Journal Materials (Basel)
Date Published 2019 Apr 18
Abstract

The effects of Ca/Si ratio, aluminum and magnesium on the carbonation behavior of calcium silicate hydrate (C-S-H) were investigated by using X-ray powder diffraction (XRD), nuclear magnetic resonance (NMR) and thermogravimetric analyzer (TGA). The results showed that the Ca/Si ratio, Al/Si ratio and Mg/Si ratio had a significant influence on the structure, carbonation products and carbonation resistance of C-(M)-(A)-S-H. The mean chain length of silicate chains in C-S-H increased as the Ca/Si ratio decreased. Aluminum uptake in C-S-H increased the content of bridging silicate tetrahedron (Q). A cross-linked structure (Q) appeared when magnesium uptake in C-S-H. The carbonation product of C-S-H was vaterite if the Ca/Si ratio was lower than 0.87. The carbonation products of C-S-H were vaterite and calcite if the Ca/Si ratio was higher than 1.02. C-M-S-H had more polymerized units, stronger bond strength and better carbonation resistance than C-S-H.

DOI 10.3390/ma12081268
ISSN 1996-1944
Citation Li J, Yu Q, Huang H, Yin S. Effects of Ca/Si Ratio, Aluminum and Magnesium on the Carbonation Behavior of Calcium Silicate Hydrate. Materials (Basel). 2019;12(8).

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