Heterobimetallic scandium-group 10 metal complexes with LM → Sc (LM = Ni, Pd, Pt) dative bonds.

Author(s) Cui, P.; Xiong, C.; Du, J.; Huang, Z.; Xie, S.; Wang, H.; Zhou, S.; Fang, H.; Wang, S.
Journal Dalton Trans
Date Published 2020 Jan 07
Abstract

Heterobimetallic scandium complexes with whole group 10 metals were synthesized. All Sc-LM complexes were characterized by NMR spectroscopy, X-ray diffraction analysis and computational studies, which revealed notable LM → Sc (LM = Ni, Pd, Pt) dative bonding interactions in these heterobimetallic systems. Versatile coordination modes toward apical donors were observed in these heterobimetallic Sc-LM complexes, among which the Sc-Ni complexes 2 and 3 were reversibly bound to N and the Sc-Pt complex 5 was coordinated to an additional PPh ligand, while in the Sc-Pd complex 4 no apical donor was ligated.

DOI 10.1039/c9dt04369a
ISSN 1477-9234
Citation Dalton Trans. 2020;49(1):124130.

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