Heterogeneous sonocatalytic degradation of an anionic dye in aqueous solution using a magnetic lanthanum dioxide carbonate-doped zinc ferrite-reduced graphene oxide nanostructure.

Author(s) Han, J.; Jun, B.M.; Heo, J.; Kim, S.; Yoon, Y.; Park, C.Min
Journal Ecotoxicol Environ Saf
Date Published 2019 Oct 30

We report herein the sonochemical synthesis of a lanthanum dioxide carbonate (LaOCO) and zinc ferrite (ZnFeO)-loaded reduced graphene oxide (LZF-rGO) nanoheterostructure for ultrasound (US)-assisted degradation of methyl orange (MO) from water. The MO was chosen as a model organic dye due to its toxicological and biodegradable-resistant properties. The LZF-rGO catalyst was characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The results of characterizations confirmed successful synthesis of sonocatalyst. Among different removal systems, US/LZF-rGO displayed outstanding sonodegradation performance for degradation of MO. The maximum removal efficiency of 75.9% was achieved using 0.2 g/L sonocatalyst, 20 mg/L MO, and 0.71 W/cm US power intensity for 65 min. MO can be partially adsorbed on LZF-rGO but mostly sonodegraded by reactive radical species. The reaction conditions were optimized by investigating the effect of key operating parameters, including the sonocatalyst dosage, initial MO concentration, US power intensity, presence of inorganic salts, and use of an enhancer, on the decolorization of MO. The degradation intermediates produced from MO during the sonocatalytic process were identified by UPLC/MS-MS, and possible mechanism and pathway for the degradation of MO in the US/LZF-rGO system were also proposed. Reusability experiments with this sonocatalyst revealed a less than 10% drop in the degradation efficiency after four adsorption-desorption cycles.

DOI 10.1016/j.ecoenv.2019.109396
Keywords Carbonates; Catalysis; Coloring Agents; Ferric Compounds; Graphite; Lanthanum; Magnetics; Microscopy, Electron, Scanning; Microscopy, Electron, Transmission; Models, Chemical; Nanostructures; Oxides; Photoelectron Spectroscopy; Water; Water Pollutants, Chemical; X-Ray Diffraction; Zinc; Zinc Compounds; Zinc Oxide
ISSN 1090-2414
Citation Ecotoxicol Environ Saf. 2019;182:109396.

Related Applications, Forms & Industries