Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate.

Author(s) Jia, J.; Ma, P.; Zhang, P.; Zhang, D.; Zhang, C.; Niu, J.; Wang, J.
Journal Dalton Trans
Date Published 2018 May 08
Abstract A monomeric trinickel(ii)-substituted phosphotungstate [H9P2W15O62Ni3]9- ion is stabilized by grafting three {Re(CO)3} organometallic groups on the surface for the first time. Magnetic measurements manifest that the resulting complex, Na(NH4)5[P2W15O56Ni3(H2O)3(μ3-OH)3(Re(CO)3)3]·18H2O (1), displays overall ferromagnetic interactions with the presence of ZFS for Ni2+ at low temperature.
DOI 10.1039/c8dt00138c
ISSN 1477-9234
Citation Dalton Trans. 2018;47(18):62886292.

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