Author(s) Zhou, Y.; Yang, S.; Huang, J.
Journal Phys Chem Chem Phys
Date Published 2017 Mar 15

In this work, we report a new photocatalytic system that links multifunctional semiconductor nanocrystals with emerging water-soluble molecular catalysts made of earth-abundant elements for H2 generation [Ni(P2(R)N2(R'))2(BF4)2](4-), R = Ph, R' = [PhSO3](-) (NiS). This noble metal free hybrid exhibits remarkable catalytic activity with a turnover number of 511 for H2 production and a photon-to-H2 conversion efficiency of 12.5%. The mechanistic insight into such high efficiency in this photocatalytic system was examined using a combination of steady-state emission and time-resolved absorption spectroscopy.

DOI 10.1039/c7cp00247e
ISSN 1463-9084
Citation Phys Chem Chem Phys. 2017;19(11):74717475.

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