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Mg(HO)BO(OH)(HO): a new hydrated borate with a short DUV cutoff edge.

Author(s) Wang, Y.; Han, J.; Guo, F.; Cheng, S.; Yang, Z.; Pan, S.
Journal Dalton Trans
Date Published 2019 Nov 26
Abstract

A new hydrated magnesium borate, Mg(H2O)6B4O5(OH)4(H2O)3, was synthesized successfully by a facile slow evaporation method. Its structure was determined by single crystal X-ray diffraction, and it contains the functional building block (FBB) [B4O5(OH)4]. It possesses a short DUV cutoff edge (<175 nm) which benefits from the absence of dangling bonds in the crystal structure. Its properties were analyzed by IR spectroscopy and UV-vis-NIR diffuse reflectance spectroscopy. Moreover, theoretical calculations were carried out to analyze the relationship between the electronic structure and optical properties.

DOI 10.1039/c9dt03401c
ISSN 1477-9234
Citation Wang Y, Han J, Guo F, Cheng S, Yang Z, Pan S. Mg(HO)BO(OH)(HO): a new hydrated borate with a short DUV cutoff edge. Dalton Trans. 2019;48(46):17408-17413.

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