Novel mononuclear Ln complexes with pyrazine-2-carboxylate and acetylacetonate co-ligands: remarkable single molecule magnet behavior of a Yb derivative.

Author(s) Gavrikov, A.V.; Efimov, N.N.; Dobrokhotova, Z.V.; Ilyukhin, A.B.; Vasilyev, P.N.; Novotortsev, V.M.
Journal Dalton Trans
Date Published 2017 Sep 12
Abstract

A series of novel isomorphic mononuclear complexes [Ln(PyrCOO)(acac)2(H2O)2] (Ln = Eu (1), Gd (2), Tb (3), Dy (4), Ho (5), Er (6), Tm (7), Yb (8), Y(9); acac- - acetylacetonate (pentane-2,4-dionate) anion, PyrCOOH is pyrazine-2-carboxylic acid) were prepared. Slow magnetic relaxation indicating SMM behavior was found in complexes 3, 4, 6 and 8. For 4 (Dy), the anisotropy barrier is Δeff/kB = 77 K under a dc field of 1500 Oe. For 8 (Yb), the anisotropy barrier is Δeff/kB = 54 K under a dc field of 2000 Oe which is the highest presently known value for molecular Yb carboxylate complexes and for Yb molecular complexes in general.

DOI 10.1039/c7dt02175e
ISSN 1477-9234
Citation Gavrikov AV, Efimov NN, Dobrokhotova ZV, Ilyukhin AB, Vasilyev PN, Novotortsev VM. Novel mononuclear Ln complexes with pyrazine-2-carboxylate and acetylacetonate co-ligands: remarkable single molecule magnet behavior of a Yb derivative. Dalton Trans. 2017;46(35):11806-11816.

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