On the use of solid-state (45)Sc NMR for structural investigations of molecular and silica-supported scandium amide catalysts.

Author(s) Vancompernolle, T.; Trivelli, X.; Delevoye, L.; Pourpoint, F.; Gauvin, R.M.
Journal Dalton Trans
Date Published 2017 Oct 10
Abstract

Tris- and tetra-coordinated scandium amides were grafted onto silica and probed as catalysts for alkyne dimerization. (45)Sc NMR was carried out, providing information about the metal coordination sphere. The increasing number of coordinated ligands was correlated with decreased catalytic activity.

DOI 10.1039/c7dt02415k
ISSN 1477-9234
Citation Vancompernolle T, Trivelli X, Delevoye L, Pourpoint F, Gauvin RM. On the use of solid-state (45)Sc NMR for structural investigations of molecular and silica-supported scandium amide catalysts. Dalton Trans. 2017;46(39):13176-13179.

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