Pd(dba)2 vs Pd2(dba)3: an in-depth comparison of catalytic reactivity and mechanism via mixed-ligand promoted C-N and C-S coupling reactions.

Author(s) Cong, M.; Fan, Y.; Raimundo, J.M.; Tang, J.; Peng, L.
Journal Org Lett
Date Published 2014 Aug 15
Abstract

With the help of mixed ligand catalytic systems, the analogous mechanisms behind the cognate performance by Pd(dba)2 and Pd2(dba)3 in catalyzing C-N and C-S coupling reactions were demonstrated. This information is instrumental in organic synthesis requiring Pd-catalyzed cross-coupling reactions and may also be valuable to other Pd-catalyzed transformations.

DOI 10.1021/ol501600k
ISSN 1523-7052
Citation Cong M, Fan Y, Raimundo J-, Tang J, Peng L. Pd(dba)2 vs Pd2(dba)3: an in-depth comparison of catalytic reactivity and mechanism via mixed-ligand promoted C-N and C-S coupling reactions. Org Lett. 2014;16(16):4074-7.

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