Phosphate amendments for chemical immobilization of uranium in contaminated soil.

Author(s) Baker, M.R.; Coutelot, F.M.; Seaman, J.C.
Journal Environ Int
Date Published 2019 Aug
Abstract

Uranium (U) contamination is a major environmental problem associated with the mining and processing of nuclear materials for both weapons and power production. When possible, in situ soil remediation techniques are preferable for reducing the risk associated with diffuse low-level U contamination. Uranium is known to form sparingly soluble phosphate compounds that persist in the environment. Therefore, batch experiments were performed to evaluate the efficacy of three phosphate amendments, hydroxyapatite (HA), sodium phytate (IP6) and sodium tripolyphosphate (TPP), to immobilize U in contaminated sediments. The amendments were added at equivalent phosphorus (P) concentrations and then equilibrated under a range of test conditions, with changes in soluble U and P monitored at pre-set time intervals. Only HA was effective at reducing the soluble U soil fraction when compared to the control, with IP6 and TPP increasing the soluble U soil fraction. After equilibration, changes in contaminant partitioning in the amended sediments were evaluated using operational extraction methods. Sequential extraction results for HA generally indicated a transfer of U from labile to more recalcitrant phases, while the results for IP6 and TPP were more ambiguous.

DOI 10.1016/j.envint.2019.03.017
ISSN 1873-6750
Citation Baker MR, Coutelot FM, Seaman JC. Phosphate amendments for chemical immobilization of uranium in contaminated soil. Environ Int. 2019;129:565-572.

Related Applications, Forms & Industries