Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes.

Author(s) Liang, Z.; Chen, J.; Chen, X.; Zhang, K.; Lv, J.; Zhao, H.; Zhang, G.; Xie, C.; Zong, L.; Jia, X.
Journal Chem Commun (Camb)
Date Published 2019 Nov 25
Abstract

A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh system.

DOI 10.1039/c9cc06834a
ISSN 1364-548X
Citation Liang Z, Chen J, Chen X, Zhang K, Lv J, Zhao H, et al. Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes. Chem Commun (Camb). 2019;55(91):13721-13724.

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