Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains.

Author(s) Schwarz, B.; Dürr, M.; Kastner, K.; Heber, N.; Ivanović-Burmazović, I.; Streb, C.
Journal Inorg Chem
Date Published 2019 Aug 15

We report the polymerization of a solvent-stabilized molecular strontium vanadium oxide monomer into infinite 1D chains. Supramolecular polymerization is triggered by controlled solvent-exchange, which leads to oligomer and polymer formation. Mechanistic insights into the chain formation were obtained by solid-state, solution, and gas-phase studies. The study shows how reactivity control of molecular metal oxides can be used to assemble complex inorganic polymeric structures.

DOI 10.1021/acs.inorgchem.9b01665
ISSN 1520-510X
Citation Inorg Chem. 2019.

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