Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate.

Author(s) Xolin, A.; Losa, R.; Kaid, A.; Tresse, C.; Beau, J.M.; Boyer, F.D.; Norsikian, S.
Journal Org Biomol Chem
Date Published 2018 Jan 03

The activation of aryl glycosyl sulfone donors has been achieved using scandium(iii) triflate and has led to the selective preparation of α-mannosides resulting from a post-glycosylation anomerization.

DOI 10.1039/c7ob02792c
ISSN 1477-0539
Citation Org Biomol Chem. 2018;16(2):325335.

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