Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate.

Author(s) Xolin, A.; Losa, R.; Kaid, A.; Tresse, C.; Beau, J.M.; Boyer, F.D.; Norsikian, S.
Journal Org Biomol Chem
Date Published 2018 Jan 03
Abstract

The activation of aryl glycosyl sulfone donors has been achieved using scandium(iii) triflate and has led to the selective preparation of α-mannosides resulting from a post-glycosylation anomerization.

DOI 10.1039/c7ob02792c
ISSN 1477-0539
Citation Xolin A, Losa R, Kaid A, Tresse C, Beau J-, Boyer F-, et al. Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate. Org Biomol Chem. 2018;16(2):325-335.

Related Applications, Forms & Industries