Synergistic ligand effect for the construction of titanium-oxo clusters with planar chirality and high solution stability.

Author(s) Ding, Q.R.; Xu, G.L.; Zhang, J.; Zhang, L.
Journal Dalton Trans
Date Published 2020 Mar 05
Abstract

A synergistic effect between dimethylglyoxime (to stabilize the Ti-O ribbon) and nonlinear dicarboxylate ligands (to bend the Ti-O ribbon) has been developed to form a series of planar chiral titanium-oxo clusters with high solution stability. The charality of the obtained clusters has been studied by X-ray structural and CD spectroscopy analysis.

DOI 10.1039/d0dt00197j
ISSN 1477-9234
Citation Ding Q-, Xu G-, Zhang J, Zhang L. Synergistic ligand effect for the construction of titanium-oxo clusters with planar chirality and high solution stability. Dalton Trans. 2020.