Syntheses and crystal structures of three [M(acac)2(TMEDA)] complexes (M = Mn, Fe and Zn).

Author(s) Halz, J.Henrik; Heiser, C.; Wagner, C.; Merzweiler, K.
Journal Acta Crystallogr E Crystallogr Commun
Date Published 2020 Jan 01
Abstract

The complexes bis-(acetyl-acetonato-κ,')(,,','-tetra-methyl-ethylenedi-amine-κ,')manganese(II), [Mn(CHO)(CHN)], bis-(acetyl-acetonato-κ,')(,,','-tetra-methyl-ethylenedi-amine-κ,')iron(II), [Fe(CHO)(CHN)], and bis-(acetyl-acetonato-κ,')(,,','-tetra-methyl-ethylenedi-amine-κ,')zinc(II), [Zn(CHO)(CHN)], were synthesized from the reaction of the corresponding metal acetyl-acetonates [(acac)(HO)] with ,,','-tetra-methyl-ethylenedi-amine (TMEDA) in toluene. Each of the complexes displays a central metal atom which is nearly octa-hedrally surrounded by two chelating acac and one chelating TMEDA ligand, resulting in an NO coordination set. Despite the chemical similarity of the complex units, the packing patterns for compounds - are different and thus the crystal structures are not isotypic.

DOI 10.1107/S2056989019016372
ISSN 2056-9890
Citation Halz JH, Heiser C, Wagner C, Merzweiler K. Syntheses and crystal structures of three [M(acac)2(TMEDA)] complexes (M = Mn, Fe and Zn). Acta Crystallogr E Crystallogr Commun. 2020;76(Pt 1):66-71.

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