Tetranuclear Dysprosium(III) Quintuple-Decker Single-Molecule Magnet Prepared Using a π-Extended Phthalocyaninato Ligand with Two Coordination Sites.

Title Tetranuclear Dysprosium(III) Quintuple-Decker Single-Molecule Magnet Prepared Using a π-Extended Phthalocyaninato Ligand with Two Coordination Sites.
Authors Katoh, K.; Morita, T.; Yasuda, N.; Wernsdorfer, W.; Kitagawa, Y.; Breedlove, B.K.; Yamashita, M.
Journal Chemistry
DOI 10.1002/chem.201804100
Abstract

We report the magnetic properties and spin relaxation processes of a tetranuclear dysprosium(III) fused phthalocyaninato quintuple-decker single-molecule magnet (1) with non-equivalent octacoordination geometries. The structure of 1 is regarded as a dimer of Dy3+-Pc triple-decker SMMs with different magnetic relaxation characteristics corresponding to the octacoordination geometry sites Dy1 with C4 symmetry (φ1 = 23°) and Dy2 with D4d symmetry (φ2 = 45°). In an Hdc of 1750 Oe and T range of 1.8-3.75 K, the quantum tunnelling of the magnetization was suppressed, and the direct process was enhanced. We examine the effects of the coordination geometry on the spin relaxation phenomena.

Citation Katoh, K.; Morita, T.; Yasuda, N.; Wernsdorfer, W.; Kitagawa, Y.; Breedlove, B.K.; Yamashita, M..Tetranuclear Dysprosium(III) Quintuple-Decker Single-Molecule Magnet Prepared Using a π-Extended Phthalocyaninato Ligand with Two Coordination Sites..

Related Elements

Dysprosium

See more Dysprosium products. Dysprosium (atomic symbol: Dy, atomic number: 66) is a Block F, Group 3, Period 6 element with an atomic radius of 162.5. Dysprosium Bohr ModelThe number of electrons in each of dysprosium's shells is [2, 8, 18, 28, 8, 2] and its electron configuration is [Xe]4f10 6s2. The dysprosium atom has an atomic radius of 178 pm and a Van der Waals radius of 229 pm. Dysprosium was first discovered by Paul Emile Lecoq de Boisbaudran in 1886. In its elemental form, dysprosium has a silvery-white appearance. Elemental Dysprosium PictureIt is a member of the lanthanide or rare earth series of elements and, along with holmium, has the highest magnetic strength of all other elements on the periodic table, especially at low temperatures. Dysprosium is found in various minerals including bastnäsite, blomstrandine, euxenite, fergusonite, gadolinite, monazite, polycrase and xenotime. It is not found in nature as a free element. The element name originates from the Greek word dysprositos, meaning hard to get at.