The coordination behaviour and reactivity of partially silicon based crown ethers towards beryllium chloride.

Author(s) Buchner, M.R.; Müller, M.; Dankert, F.; Reuter, K.; von Hänisch, C.
Journal Dalton Trans
Date Published 2018 Nov 27

Through reactions of 1,2-disila[12]crown-4 or 1,2-disila-benzo[12]crown-4 ethers with BeCl2 eight-membered Be-O-heterocycles, which are annulated by two six-membered Be-O-cycles were obtained and characterised. The reactions leading to these unusual ring systems have been investigated by NMR and IR spectroscopy as well as reactions with further ligand derivatives.

DOI 10.1039/c8dt03963a
ISSN 1477-9234
Citation Dalton Trans. 2018;47(46):1639316397.

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