The effects of altering reaction conditions in green sonochemical synthesis of a thallium(I) coordination polymer and in achieving to different morphologies of thallium(III) oxide nanostructures via solid-state process.

Author(s) Hazrati, Z.; Akhbari, K.; Phuruangrat, A.
Journal Ultrason Sonochem
Date Published 2017 Nov

In order to studies the effects of solvent and concentration of initial reagents on formation of [Tl(μ4-AB)]n (1), [HAB=4-aminobenzoic acid] coordination polymer, some experiments were designed and four samples of 1 were synthesized by sonochemical process. High concentration of initial reagents resulted in formation of compound 1 microrods. With low concentration of initial reagents, various morphologies of 1 were obtained. These four samples had been used as new precursors for preparation of thallium(III) oxide nanostructures via solid-state thermal decomposition process. One- and two-dimensional nanostructures of thallium(III) oxide can be prepared from 1. These micro and nanostructures were characterized by IR spectroscopy, X-ray powder diffraction (XRD) and Scanning Electron Microscopy (SEM).

DOI 10.1016/j.ultsonch.2017.05.037
ISSN 1873-2828
Citation Ultrason Sonochem. 2017;39:662668.

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