Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions.

Author(s) Zottnick, S.H.; Finze, M.; Müller-Buschbaum, K.
Journal Chem Commun (Camb)
Date Published 2017 Apr 26
Abstract

The lanthanum tetracyanoborate coordination polymers [EMIM] [LaNO3{B(CN)4}3(H2O)3] (EMIM = 1-ethyl-3-methylimidazolium) and [La(NO3)2[B(CN)4](H2O)4] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Thereby, the ionic liquid [EMIM][B(CN)4] is fully incorporated into product formation.

DOI 10.1039/c7cc01378g
ISSN 1364-548X
Citation Zottnick SH, Finze M, Müller-Buschbaum K. Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions. Chem Commun (Camb). 2017.

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