Unprecedented one-pot reaction to chiral, non-racemic copper(I) complexes of [2.2]paracyclophane-based P,N-ligands.

Author(s) Braun, C.; Nieger, M.; Bräse, S.
Journal Chemistry
Date Published 2017 Oct 02
Abstract

Herein, we report a simple one-pot reaction to enantiopure copper(I) complexes featuring a unique [2.2]paracyclophane-based P,N-ligand system. Phosphine and pyridine moiety can be varied allowing the modular synthesis of these rigid and stable [2.2]paracyclophane-based P,N-ligands. These P,N-ligands are a new ligand class for different transition metal complexes, which is shown exemplarily for palladium(II).

DOI 10.1002/chem.201704115
ISSN 1521-3765
Citation Braun C, Nieger M, Bräse S. Unprecedented one-pot reaction to chiral, non-racemic copper(I) complexes of [2.2]paracyclophane-based P,N-ligands. Chemistry. 2017.

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