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Rhodium(III) Acetate

CAS #:

Linear Formula:

Rh(C2H3O2)3

MDL Number:

MFCD22495369

EC No.:

247-460-0

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Rhodium(III) Acetate
RH3-AC-02-C
Pricing > SDS > Data Sheet >
(3N) 99.9% Rhodium(III) Acetate
RH3-AC-03-C
Pricing > SDS > Data Sheet >
(4N) 99.99% Rhodium(III) Acetate
RH3-AC-04-C
Pricing > SDS > Data Sheet >
(5N) 99.999% Rhodium(III) Acetate
RH3-AC-05-C
Pricing > SDS > Data Sheet >

Rhodium(III) Acetate Properties (Theoretical)

Compound Formula C6H9O6Rh
Molecular Weight 280.04
Appearance Green crystals or crystalline powder
Melting Point N/A
Boiling Point 117.1 °C
Density N/A
Solubility in H2O N/A
Exact Mass 279.945417 g/mol
Monoisotopic Mass 279.945417 g/mol

Rhodium(III) Acetate Health & Safety Information

Signal Word Warning
Hazard Statements H302-H315-H319-H335
Hazard Codes Xi
Precautionary Statements P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501
Risk Codes R22-R36/37/38
Safety Statements S1-S20/21-S23-S26-S27-S28-S28B-S36/37/39-S44-S46-S51-S61-S7/9
Transport Information NONH for all modes of transport
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/17/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Rhodium(III) Acetate

Product Number: All applicable American Elements product codes, e.g. RH3-AC-02-C 02 , RH3-AC-03-C 03 , RH3-AC-04-C 04 , RH3-AC-05-C 05

CAS #: 26105-49-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, oral(Category 4)
H302
Skin corrosion/irritation(Category 2)
H315
Serious eye damage/eye irritation(Category 2A )
H319
Specific target organ toxicity, single exposure(Category 3)
H335
No Resource File
2.2 GHS Label elements, including precautionary statements

Exclamation Mark - GHS07

Pictogram
Signal word
Warning
Hazard statement(s)
H302
Harmful if swallowed
H315
Causes skin irritation
H319
Causes serious eye irritation
H335
May cause respiratory irritation
Precautionary statement(s)
P261
Avoid breathing dust/fume/gas/mist/vapors/spray.
P264
Wash hands thoroughly after handling
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352
IF ON SKIN: Wash with plenty of soap and water.
P304+P340
IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312
Call a POISON CENTER or doctor/physician if you feel unwell.
P330
Rinse mouth.
P332+P313
If skin irritation occurs: Get medical advice/attention.
P337+P313
If eye irritation persists: Get medical advice/attention.
P362
Take off contaminated clothing and wash before reuse.
P403+P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
P501
Dispose of contents/container to in accordance with local regulation
2.3 Associated risk phrases according to european directive 67/548/EEC
Hazard symbol(s)
R-phrase(s)
R22
Harmful if swallowed.
R36
Irritating to eyes.
R37
Irritating to respiratory system.
R38
Irritating to skin.
S-phrase(s)
S1
Keep locked up.
S20/21
When using do not eat, drink or smoke.
S23
Do not breathe gas/fumes/Vapor/spray.
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27
Take off immediately all contaminated clothing.
S28
After contact with skin, wash immediately with plenty of water.
S28B
After contact with skin, wash immediately with plenty of water and soap.
S36/37/39
Wear suitable protective clothing, gloves and eye/face protection.
S44
If you feel unwell, seek medical advice (show the label where possible).
S46
If swallowed, seek medical advice immediately and show this container or label.
S51
Use only in well-ventilated areas.
S61
Avoid release to the environment. Refer to special instructions/Safety data sheets.
S7/9
Keep container tightly closed and in a well-ventilated place


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Molecular Formula:
C6H9O6Rh
Molecular Weight:
280.04g/mol
Component
Concentration
Rhodium(III) acetate
CAS Number
26105-49-7
-


SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during transport to hospital.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available


SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing media: alcohol-resistant foam, dry chemical or carbon dioxide
Unsuitable extinguishing media: no date
5.2 Special hazards arising from the substance or mixture
In combustion toxic fumes may form.
5.3 Advice for firefighters
Wear self-contained breathing apparatus.
Wear protective clothing to prevent contact with skin and eyes.


SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Do not attempt to take action without suitable protective clothing.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains or river.
Alert the neighbourhood to the presence of fumes or gas.
6.3 Methods and materials for containment and cleaning up
Mix with sand or vermiculite. Sweep up and shovel. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
6.4 Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Ensure there is sufficient ventilation of the area.
Normal measures for preventive fire protection. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated area. Containers which are opened must be carefully resealed and kept upright to prevent leakage.Store at 2-8 °C.
7.3 Specific end use(s)
The end use(s) have not been fully determined. The substance is supplied for Research and Development purposes by professionals only.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Solid
Boiling Point
117.1°C
Melting Point
No data available
Odor
No date available
Odor Threshold
No data available
pH
No data available
Flash point
40°C
EVaporation rate
No data available
Vapor pressure
No data available
Vapor Density
No data available
Relative density
No data available
Solubility in water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity No Data
No data available
Explosive properties
No data available
Oxidizing properties
No data available


SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
Carbon monoxide, carbon dioxide..


SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute Toxicity
No date available
Skin corrosion/irritation
Irritant for skin and mucous membranes
Serious eye Damage/irritation
Irritant effect
Respiratory or skin sensitisation
No date available
Germ Cell mutagenicity
No date available
Carcinogenicity
No date available
Reproductive toxicity
No date available
STOT-single exposure
No date available
STOT-repeated exposure
No date available
Aspiration hazard
No date available
11.2 Additional
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC,NTP,OSHA or ACGIH


SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
No data available.
12.2 Persistence and degradability
No data available.
12.3 Bioaccumulative potential
No data available.
12.4 Mobility in soil
No data available.
12.5 Results of PBT and vPvB assessment
No data available.
12.6 Other adverse effects
No data available.


SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Disposal Operations
Consult official regulations for proper disposal. Hand over to authorised disposal company as hazardous waste.
Disposal of Packaging
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental and national regulations:
Product is not subject to any additional regulations or provisions
Safety Assessment
No Chemical Safety Assessment


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Rhodium(III) Acetate

Acetate Formula StructureRhodium(III) Acetate is a moderately water soluble crystalline Rhodium source that decomposes to Rhodium oxide on heating. It is generally immediately available in most volumes. All metallic acetates are inorganic salts containing a metal cation and the acetate anion, a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. Acetates are excellent precursors for production of ultra high purity compounds, catalysts, and nanoscale materials. We also produce Rhodium Acetate Solution. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Rhodium(III) Acetate Synonyms

Rhodium(3+) triacetate, Acetic acid, rhodium(3+) salt, Rhodium triacetate

Chemical Identifiers

Linear Formula Rh(C2H3O2)3
MDL Number MFCD22495369
EC No. 247-460-0
Beilstein Registry No. N/A
Pubchem CID 168478
IUPAC Name rhodium(3+); triacetate
SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Rh+3]
InchI Identifier InChI=1S/3C2H4O2.Rh/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
InchI Key SVOOVMQUISJERI-UHFFFAOYSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Rhodium products. Rhodium (atomic symbol: Rh, atomic number: 45) is a Block D, Group 9, Period 5 element with an atomic weight of 102.90550. Rhodium Bohr ModelThe number of electrons in each of Rhodium's shells is [2, 8, 18, 16, 1] and its electron configuration is [Kr] 4d8 5s1. The rhodium atom has a radius of 134 pm and a Van der Waals radius of 195 pm. Rhodium was discovered and first isolated by William Wollaston in 1804. In its elemental form, rhodium has a silvery white metallic appearance. Elemental RhodiumRhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density. Rhodium is found in ores mixed with other metals such as palladium, silver, platinum, and gold. Rhodium is primarily used as the catalyst in the three-way catalytic converters of automobiles it is also highly valued in jewelry. The name Rhodium originates from the Greek word 'Rhodon,' which means rose.

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November 17, 2019
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