Rhodium(III) and Iridium(III) Bipyricorrole Complexes: Syntheses, Structures, and Properties.

Title Rhodium(III) and Iridium(III) Bipyricorrole Complexes: Syntheses, Structures, and Properties.
Authors B. Adinarayana; M. Murugavel; M. Das; N.Rao Palepu; A. Srinivasan
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b02724
Abstract

Rhodium(III) and iridium(III) bipyricorrole complexes have been unprecedentedly reported. Single-crystal X-ray diffraction studies unambiguously evinced the molecular structures of metal complexes in octahedral geometry. The monoanionic platform of bipyricorrole effectively stabilizes metal ions in their higher oxidation states. It is worth mentioning that the fluorescence quantum yield of the rhodium(III) complex is 3-fold higher than that of free-base bipyricorrole.

Citation B. Adinarayana; M. Murugavel; M. Das; N.Rao Palepu; A. Srinivasan.Rhodium(III) and Iridium(III) Bipyricorrole Complexes: Syntheses, Structures, and Properties.. Inorg Chem. 2018. doi:10.1021/acs.inorgchem.7b02724

Related Elements

Iridium

See more Iridium products. Iridium (atomic symbol: Ir, atomic number: 77) is a Block D, Group 9, Period 6 element with an atomic weight of 192.217. The number of electrons in each of iridium's shells is [2, 8, 18, 32, 15, 2] and its electron configuration is [Xe] 4f14 5d7 6s2. Iridium Bohr ModelThe iridium atom has a radius of 136 pm and a Van der Waals radius of 202 pm. Iridium was discovered and first isolated by Smithson Tennant in 1803. In its elemental form, Iridium has a silvery white appearance. Iridium is a member of the platinum group of metals.Elemental Iridium It is the most corrosion resistant metal known and is the second-densest element (after osmium). It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. Iridium is found as an uncombined element and in iridium-osmium alloys. Iridium's name is derived from the Greek goddess Iris, personification of the rainbow, on account of the striking and diverse colors of its salts.

Rhodium

See more Rhodium products. Rhodium (atomic symbol: Rh, atomic number: 45) is a Block D, Group 9, Period 5 element with an atomic weight of 102.90550. Rhodium Bohr ModelThe number of electrons in each of Rhodium's shells is [2, 8, 18, 16, 1] and its electron configuration is [Kr] 4d8 5s1. The rhodium atom has a radius of 134 pm and a Van der Waals radius of 195 pm. Rhodium was discovered and first isolated by William Wollaston in 1804. In its elemental form, rhodium has a silvery white metallic appearance. Elemental RhodiumRhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density. Rhodium is found in ores mixed with other metals such as palladium, silver, platinum, and gold. Rhodium is primarily used as the catalyst in the three-way catalytic converters of automobiles it is also highly valued in jewelry. The name Rhodium originates from the Greek word 'Rhodon,' which means rose.

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