Screened Charge Carrier Transport in Methylammonium Lead Iodide Perovskite Thin Films.

Title Screened Charge Carrier Transport in Methylammonium Lead Iodide Perovskite Thin Films.
Authors A.H. Hill; K.E. Smyser; C.L. Kennedy; E.S. Massaro; E.M. Grumstrup
Journal J Phys Chem Lett
DOI 10.1021/acs.jpclett.7b00046
Abstract

While organometal halide perovskites are promising for a variety of optoelectronic applications, the morphological and compositional defects introduced by solution processing techniques have hindered efforts at understanding their fundamental properties. To provide a detailed picture of the intrinsic carrier transport properties of methylammonium lead iodide without contributions from defects such as grain boundaries, we utilized pump-probe microscopy to measure diffusion in individual crystalline domains of a thin film. Direct imaging of carrier transport in 25 individual domains yields diffusivities between 0.74 and 1.77 cm^2 s^-1, demonstrating single-crystal-like, long-range transport characteristics in a thin film architecture. We also examine the effects of excitation density on carrier diffusivity, finding that transport is nearly independent of photoexcited carrier density between 6×10^17 cm^-3 and 4×10^19 cm^-3. Transport modeling of the observed density independence suggests that strong carrier-phonon scattering coupled with a large static relative permittivity is responsible for the unusual transport characteristics of methylammonium perovskite.

Citation A.H. Hill; K.E. Smyser; C.L. Kennedy; E.S. Massaro; E.M. Grumstrup.Screened Charge Carrier Transport in Methylammonium Lead Iodide Perovskite Thin Films.. J Phys Chem Lett. 2017. doi:10.1021/acs.jpclett.7b00046

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