Silver-doped molybdenum carbide catalyst with high activity for electrochemical water splitting.

Title Silver-doped molybdenum carbide catalyst with high activity for electrochemical water splitting.
Authors X. Li; X. Ma; X. Du; J. Zheng; X. Hao; A. Abudula; G. Guan
Journal Phys Chem Chem Phys
DOI 10.1039/c6cp06307a
Abstract

A hybrid catalyst composed of silver (Ag) doped wire-like molybdenum carbide (MoxCy) with pure ?-phase and carbon nanotubes (CNTs) was coated well on a carbon rod electrode for the hydrogen evolution reaction (HER). The effects of Ag loading amount and carbonization temperature on the crystal form of MoxCy were investigated in detail. It is found that the MoxCy crystal form can be tuned by adjusting the preparation conditions, and nanostructured wire-like Mo2C with pure ?-phase was obtained at a temperature over 750 °C. Ag/MoxCy composite nanomaterials were investigated by X-ray diffraction, UV/vis spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, energy-dispersive spectroscopy and Brunauer-Emmett-Teller surface area analysis. The hybrid catalyst was further deposited on the carbon nanotube (CNT) modified carbon rod substrate. Due to the high surface area and 3D porous network-like microstructure, the Ag/Mo2C/CNTs hybrid electrode showed enhanced catalytic performance when comparing with the corresponding pure one. Particularly, for the Ag-doped Mo2C/CNTs hybrid electrode with an optimum 1 Ag?:?5 Mo molar ratio of the precursors, a current density of 10 mA cm(-2) was obtained by applying an overpotential of 142 mV in 0.5 mol L(-1) H2SO4 solution. It is expected that such a hybrid electrode can be widely applied for effective electrolysis of water to produce hydrogen.

Citation X. Li; X. Ma; X. Du; J. Zheng; X. Hao; A. Abudula; G. Guan.Silver-doped molybdenum carbide catalyst with high activity for electrochemical water splitting.. Phys Chem Chem Phys. 2016;18(48):3278032785. doi:10.1039/c6cp06307a

Related Elements

Molybdenum

See more Molybdenum products. Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. Elemental MolybdenumIt has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead.

Silver

See more Silver products. Silver (atomic symbol: Ag, atomic number: 47) is a Block D, Group 11, Period 5 element with an atomic weight of 107.8682. Silver Bohr ModelThe number of electrons in each of Silver's shells is 2, 8, 18, 18, 1 and its electron configuration is [Kr]4d10 5s1. The silver atom has a radius of 144 pm and a Van der Waals radius of 203 pm. Silver was first discovered by Early Man prior to 5000 BC. In its elemental form, silver has a brilliant white metallic luster. Elemental SilverIt is a little harder than gold and is very ductile and malleable, being exceeded only by gold and perhaps palladium. Pure silver has the highest electrical and thermal conductivity of all metals and possesses the lowest contact resistance. It is stable in pure air and water, but tarnishes when exposed to ozone, hydrogen sulfide, or air containing sulfur. It is found in copper, copper-nickel, lead, and lead-zinc ores, among others. Silver was named after the Anglo-Saxon word "seolfor" or "siolfur," meaning 'silver'.

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