Sodium Oxide

CAS #

Na2O

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PRODUCT PRODUCT CODE REQUEST A QUOTE PRINT SAFETY DATA
80% Sodium Oxide NA-OX-80 Request Quote

Properties

Compound Formula Na2O
Molecular Weight 61.97
Appearance Yellow Crystalline Solid
Melting Point 1,132° C (2,070° F)
Boiling Point 1,950° C (3,542° F)
Density 2.27 g/cm3
Monoisotopic Mass 61.974453 g/mol
Exact Mass 61.974453 g/mol

Health & Safety Information

Signal Word Danger
Hazard Statements H271-H314
Hazard Codes O,C
Risk Codes 8-14-35
Safety Statements 8-27-39-43-45
RTECS Number N/A
Transport Information UN 3085 8(5.1) / PGI
WGK Germany 1

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SAFETY DATA SHEET

Date Accessed: 02/13/2016
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Sodium Oxide

Product Number: All applicable American Elements product codes, e.g. NA-OX-80

CAS #: 1313-59-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
Hazards not otherwise classified No information known.
Label elements
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Corrosion - GHS05

GHS05
Signal word Danger
Hazard statements
H314 Causes severe skin burns and eye damage.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
E - Corrosive material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
3

2
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
1313-59-3 Sodium oxide
Identification number(s):
EC number: 215-208-9


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information Immediately remove any clothing soiled by the product.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents Water
Special hazards arising from the substance or mixture
Reacts violently with water
If this product is involved in a fire, the following can be released:
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Use neutralizing agent.
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires: No information known.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from air.
Store away from water/moisture.
Further information about storage conditions:
Store under dry inert gas.
This product is moisture sensitive.
This product is air sensitive.
Protect from humidity and water.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes) Not determined
Eye protection:
Tightly sealed goggles
Full face protection
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder, beads, or solid in various forms
Color: White to grey
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: >400 °C (>752 °F) (dec)
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous) Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 2.27 g/cm³ (18.943 lbs/gal)
Relative density Not determined.
Vapor density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
Water: Reacts violently
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity Reacts violently with water.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions Reacts violently with water
Conditions to avoid No further relevant information available.
Incompatible materials:
Acids
Air
Water/moisture
Hazardous decomposition products: Carbon monoxide and carbon dioxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Causes severe skin burns.
Eye irritation or corrosion: Causes serious eye damage.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: No effects known.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN1825
UN proper shipping name
DOT Sodium monoxide
IMDG, IATA SODIUM MONOXIDE
Transport hazard class(es)
DOT
Class 8 Corrosive substances.
Label 8
Class 8 (C6) Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances.
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Corrosive substances
EMS Number: F-A,S-B
Segregation groups Alkalis
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN1825, Sodium monoxide, 8, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS05
Signal word Danger
Hazard statements
H314 Causes severe skin burns and eye damage.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings) Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Oxide IonSodium Oxide is a highly insoluble thermally stable Sodium source suitable for glass, optic and ceramic applications. Oxide compounds are not conductive to electricity. However,High Purity (99.999%) sodium Oxide (NaO2)Powder certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. They are compounds containing at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advanced electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic conductivity. Metal oxide compounds are basicanhydrides and can therefore react with acids and with strong reducing agents in redox reactions. Sodium Oxide is also available in pellets, pieces, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). See Nanotechnology for more nanotechnology applications information. Sodium Oxide is generally immediately available in most volumes. Ultra high purity, high purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Disodium monoxide, Disodium oxide, Disodium oxygen(-2) anion, Disodium hydroxide, Sodium superoxide

Chemical Identifiers

Formula Na2O
CAS 1313-59-3
Pubchem CID 73971
MDL MFCD00046201
EC No. 215-208-9
IUPAC Name disodium; oxygen(2-)
Beilstein Registry No. N/A
SMILES [Na+].[Na+].[O-2]
InchI Identifier InChI=1S/2Na.O/q2*+1;-2
InchI Key KKCBUQHMOMHUOY-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Products & Element Information

Sodium Bohr ModelSee more Sodium products. Sodium (atomic symbol: Na, atomic number: 11) is a Block D, Group 5, Period 4 element with an atomic weight of 22.989769. The number of electrons in each of Sodium's shells is [2, 8, 1] and its electron configuration is [Ne] 3s1.The sodium atom has a radius of 185.8 pm and a Van der Waals radius of 227 pm. Sodium was discovered and first isolated by Sir Humphrey Davy in 1807. In its elemental form, sodium has a silvery-white metallic appearance. It is the sixth most abundant element, making up 2.6 % of the earth's crust. Sodium does not occur in nature as a free element and must be extracted from its compounds (e.g., feldspars, sodalite, and rock salt). The name Sodium is thought to come from the Arabic word suda, meaning "headache" (due to sodium carbonate's headache-alleviating properties), and its elemental symbol Na comes from natrium, its Latin name.

Recent Research

Survival mechanism of Escherichia coli O157:H7 against combined treatment with acetic acid and sodium chloride., Lee, Sun-Young, and Kang Dong-Hyun , Food Microbiol, 2016 May, Volume 55, p.95-104, (2016)

Adsorption configuration of sodium 2-quinoxalinecarboxylate on iron substrate: Investigation by in situ SERS, XPS and theoretical calculation., Huo, Sheng-Juan, He Jin-Mei, Chen Li-Hong, and Fang Jian-Hui , Spectrochim Acta A Mol Biomol Spectrosc, 2016 Mar 5, Volume 156, p.123-30, (2016)

Differential proteomics to explore the inhibitory effects of acidic, slightly acidic electrolysed water and sodium hypochlorite solution on Vibrio parahaemolyticus., Chen, Tai-Yuan, Kuo Shu-Hao, Chen Shui-Tein, and Hwang Deng-Fwu , Food Chem, 2016 Mar 1, Volume 194, p.529-37, (2016)

Catalytic effect of potassium in Na1-xKxCdPb3(PO4)3 to detect mercury (II) in fish and seawater using a carbon paste electrode., Lahrich, S, Manoun B, and Mhammedi M A. El , Talanta, 2016 Mar 1, Volume 149, p.158-67, (2016)

Short-term effects of povidone iodine and sodium fluoride therapy on plaque levels and microbiome diversity., Reilly, C, Goettl M, Steinmetz M, Nikrad J, and Jones R S. , Oral Dis, 2016 Mar, Volume 22, Issue 2, p.155-61, (2016)

Pretreatment combining ultrasound and sodium percarbonate under mild conditions for efficient degradation of corn stover., Nakashima, Kazunori, Ebi Yuuki, Kubo Masaki, Shibasaki-Kitakawa Naomi, and Yonemoto Toshikuni , Ultrason Sonochem, 2016 Mar, Volume 29, p.455-60, (2016)

Sodium butyrate attenuates social behavior deficits and modifies the transcription of inhibitory/excitatory genes in the frontal cortex of an autism model., Kratsman, Neta, Getselter Dmitriy, and Elliott Evan , Neuropharmacology, 2016 Mar, Volume 102, p.136-45, (2016)

Enhancement effects of ultrasound on secondary wastewater effluent disinfection by sodium hypochlorite and disinfection by-products analysis., Zhou, Xiaoqin, Zhao Junyuan, Li Zifu, Song Jianing, Li Xueying, Yang Xin, and Wang Dongling , Ultrason Sonochem, 2016 Mar, Volume 29, p.60-6, (2016)

Initial hydration behavior of sodium iodide dimer: photoelectron spectroscopy and ab initio calculations., Li, Ren-Zhong, Hou Gao-Lei, Liu Cheng-Wen, Xu Hong-Guang, Zhao Xiang, Gao Yi Qin, and Zheng Wei-Jun , Phys Chem Chem Phys, 2016 Jan 7, Volume 18, Issue 1, p.557-65, (2016)

Tracking sodium-antimonide phase transformations in sodium-ion anodes; insights from operando pair distribution function analysis and solid-state NMR spectroscopy., Allan, Phoebe K., Griffin John M., Darwiche Ali, Borkiewicz Olaf J., Wiaderek Kamila M., Chapman Karena W., Morris Andrew J., Chupas Peter J., Monconduit Laure, and Grey Clare P. , J Am Chem Soc, 2016 Jan 29, (2016)