Surface Roughening of Nickel Cobalt Phosphide Nanowire Arrays/Ni Foam for Enhanced Hydrogen Evolution Activity.

Title Surface Roughening of Nickel Cobalt Phosphide Nanowire Arrays/Ni Foam for Enhanced Hydrogen Evolution Activity.
Authors X. Wang; R. Tong; Y. Wang; H. Tao; Z. Zhang; H. Wang
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.6b07226
Abstract

Development of earth-abundant, efficient, and stable electrocatalysts for hydrogen evolution reactions (HER) in alkaline or even neutral pH electrolyte is very important for hydrogen production from water splitting. Construction of bimetal phosphides via tuning the bonding strength to hydrogen and increasing effective active sites through nanostructuring and surface engineering should lead to high HER activity. Here, ternary NiCoP nanowires (NWs) decorated by homogeneous nanoparticles have been obtained on Ni foam for a highly efficient HER property via long-term cyclic voltammetric (CV) sweeping. The electron density transfer between the positively charged Ni and Co and negatively charged P atoms, one-dimensional electron transfer channel of the NWs, and abundant active sites supplied by the nanoparticles and NWs endow the catalyst with low overpotentials of 43 and 118 mV to achieve the respective current densities of 10 and 100 mA cm(-2) together with long durability for at least 33 h in 1 M KOH. A cycled anodic dissolution-redeposition mechanism is disclosed for the formation of the NiCoP nanoparticles during the CV sweeping process. Such a surface roughening method is found to be adaptable to enhance the HER property of other phosphides, including Ni2P nanoplates/NF, NiCoP nanoparticles/NF, and CoP NW/NF.

Citation X. Wang; R. Tong; Y. Wang; H. Tao; Z. Zhang; H. Wang.Surface Roughening of Nickel Cobalt Phosphide Nanowire Arrays/Ni Foam for Enhanced Hydrogen Evolution Activity.. ACS Appl Mater Interfaces. 2016;8(50):3427034279. doi:10.1021/acsami.6b07226

Related Elements

Cobalt

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar]3d7 4s2. The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit.

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

Phosphorus

Phosphorus Bohr ModelSee more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.