Surfactant mediated synthesis of bismuth selenide thin films for photoelectrochemical solar cell applications.

Title Surfactant mediated synthesis of bismuth selenide thin films for photoelectrochemical solar cell applications.
Authors N.D. Desai; K.V. Khot; V.B. Ghanwat; S.D. Kharade; P.N. Bhosale
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2017.12.038
Abstract

In the present report, nanostructured bismuth selenide (BiSe) thin films have been successfully deposited by using arrested precipitation technique (APT) at room temperature. The effect of three different surfactants on the optostructural, morphological, compositional and photoelectrochemical properties of BiSethin films were investigated. Optical absorption data indicates direct and allowed transition with a band gap energy varied from 1.4?eV to 1.8?eV. The X-ray diffraction pattern (XRD) revealed that BiSethin films are crystalline in nature and confirmed rhombohedral crystal structure. SEM micrographs shows morphological transition from interconnected mesh to nanospheres like and finally granular morphology. Surface topography of BiSethin films was determined by AFM. Compositional analysis of all samples was carried out by energy dispersive X-ray spectroscopy (EDS). Finally, all BiSethin films shows good PEC performance with highest photoconversion efficiency 1.47%. In order to study the stability of BiSethin films four cycles are repeated after gap of one week each. Further PEC performance of all BiSethin films are also supported by electrochemical impedance (EIS) measurement study.

Citation N.D. Desai; K.V. Khot; V.B. Ghanwat; S.D. Kharade; P.N. Bhosale.Surfactant mediated synthesis of bismuth selenide thin films for photoelectrochemical solar cell applications.. J Colloid Interface Sci. 2018;514:250261. doi:10.1016/j.jcis.2017.12.038

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Bismuth

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