Synthesis of praseodymium hydroxide (Pr(OH)3) and praseodymium oxide (Pr6O11) nanorods via room temperature aging.

Title Synthesis of praseodymium hydroxide (Pr(OH)3) and praseodymium oxide (Pr6O11) nanorods via room temperature aging.
Authors A. Dodd
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2012.10.001
Abstract

In this study, room-temperature aging has been investigated as an alternative to high-temperature hydrothermal processing for manufacturing Pr(OH)(3) nanorods. It was found that a simple process consisting of precipitation, washing, and room-temperature aging results in the formation of Pr(OH)(3) nanorods that are structurally different to those synthesized by hydrothermal processing. Rather than single crystals, the nanorods were found to consist of crystals viewed down the [12¯10] and [11¯00] axes sharing a common [0001] growth direction. Subsequent calcination yielded Pr(6)O(11) nanorods consisting of cubic crystals viewed down the [11¯0] and [11¯2¯] directions. The constituent crystals shared a common [110] direction parallel with the longitudinal rod axis.

Citation A. Dodd.Synthesis of praseodymium hydroxide (Pr(OH)3) and praseodymium oxide (Pr6O11) nanorods via room temperature aging.. J Colloid Interface Sci. 2013;392:13740. doi:10.1016/j.jcis.2012.10.001

Related Elements

Praseodymium

See more Praseodymium products. Praseodymium (atomic symbol: Pr, atomic number: 59) is a Block F, Group 3, Period 6 element with an atomic weight of 140.90765. Praseodymium Bohr Model The number of electrons in each of praseodymium's shells is 2, 8, 18, 21, 8, 2 and its electron configuration is [Xe]4f3 6s2. The praseodymium atom has a radius of 182 pm and a Van der Waals radius of 239 pm. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Elemental PraseodymiumUnlike other rare-earth metals, which show antiferromagnetic and / or ferromagnetic ordering at low temperatures, praseodymium is paramagnetic at any temperature above 1 K. Praseodymium is found in the minerals monazite and bastnasite. Praseodymium was discovered by Carl Auer von Welsbach in 1885. The origin of the element name comes from the Greek words prasios didymos, meaning green twin.

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