SECTION 2. HAZARDS IDENTIFICATION

Classification
Classification under 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute oral toxicity
Category 2
Acute dermal toxicity
Category 2
Acute Inhalation Toxicity - Dusts and Mists
Category 2
Specific target organ toxicity - (repeated exposure)
Category 2
Target Organs -
Liver, kidney, and respiratory system, Central nervous system (CNS), Cardiovascular system.
Label Elements

Signal Word
Danger
Hazard Statements
Fatal if swallowed
Fatal in contact with skin
Fatal if inhaled
May cause damage to organs through prolonged or repeated exposure
Precautionary Statements
Prevention
Use only outdoors or in a well-ventilated area
Wear protective gloves/protective clothing/eye protection/face protection
In case of inadequate ventilation wear respiratory protection
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not get in eyes, on skin, or on clothing
Wash face, hands and any exposed skin thoroughly after handling
Response
IF exposed or concerned: Get medical attention/advice
Inhalation
Immediately call a POISON CENTER or doctor/physician
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
Immediately call a POISON CENTER or doctor/physician
Take off contaminated clothing and wash before reuse
IF ON SKIN: Wash with plenty of soap and water
Ingestion
Rinse mouth
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Toxic to aquatic life with long lasting effects
Other hazards
May cause eye, skin, and respiratory tract irritation. May cause pulmonary edema.
NFPA :
Health
4
Flammability
0 
Instability
0 
Physical hazards
N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Product name: Thallium(I) malonate
CAS number: 2757-18-8
EC-No.: 231-138-1
Molecular formula: CH2(COOTl)2

SECTION 4. FIRST AID MEASURES

Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Obtain medical attention.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth
resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a
respiratory medical device. Immediate medical attention is required.
Ingestion
Do not induce vomiting. Call a physician or Poison Control Center immediately.
Most important symptoms/effects
No data available.
Notes to Physician
Treat symptomatically

SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
No data available
Flash Point
No data available
Method -
No data available
Autoignition Temperature
No data available
Explosion Limits
Upper: No data available
Lower: No data available
Sensitivity to Mechanical Impact
No data available
Sensitivity to Static Discharge
No data available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Carbon monoxide (CO) Carbon dioxide (CO2) Fumes
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions
Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation.
Avoid contact with skin, eyes and clothing.
Environmental Precautions
See Section 12 for additional ecological information.
Methods for Containment and Clean Up
Sweep up or vacuum up spillage and collect in suitable container for disposal.

SECTION 7. HANDLING AND STORAGE

Handling
Ensure adequate ventilation. Wear personal protective equipment. Avoid dust formation.
Avoid contact with skin, eyes and clothing. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not ingest. Remove and wash contaminated clothing before re-use.
Storage
Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Component: Thallous malonate
ACGIH TLV: TWA: 0.02 mg/m3 Skin
OSHA PEL: Skin
NIOSH IDLH:
IDLH: 15 mg/m3
TWA: 0.1 mg/m3
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
NIOSH IDLH:
The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering Measures
Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Appearance: White
Odor: No data available
Odor Threshold: No data available
pH: No data available
Melting Point/Range: No data available
Boiling Point/Range: No data available
Flash Point: No data available
Evaporation Rate: No data available
Flammability (solid,gas): No data available
Flammability or explosive limits
Upper: No data available
Lower: No data available
Vapor Pressure: No data available
Vapor Density: No data available
Relative Density: No data available
Solubility: No data available
Partition coefficient; n-octanol/water: No data available
Autoignition Temperature: No data available
Decomposition Temperature: No data available
Viscosity: No data available
Molecular Formula: C3 H2 O4 Tl2
Molecular Weight: 510.8

SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard
None known, based on information available
Stability
Stable under normal conditions.
Conditions to Avoid
Incompatible products. Excess heat. Avoid dust formation.
Incompatible Materials
Strong oxidizing agents
Hazardous Decomposition Products
Carbon monoxide (CO), Carbon dioxide (CO2), Fumes
Hazardous Polymerization
Hazardous polymerization does not occur.
Hazardous Reactions
None under normal processing.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information: No acute toxicity information is available for this product
Toxicologically Synergistic Products: No data available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation: May cause eye, skin, and respiratory tract irritation
Sensitization: No data available
Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutagenic Effects: No data available
Reproductive Effects: No data available.
Developmental Effects: No data available.
Teratogenicity: No data available.
STOT - single exposure: None known
STOT - repeated exposure
Liver, kidney, and respiratory system Central nervous system (CNS) Cardiovascular system
Aspiration hazard: No data available
Symptoms / effects,both acute and delayed: No data available
Endocrine Disruptor Information: No data available
Other Adverse Effects
May cause conjunctivitis. Prolonged and/or repeated contact may cause irritation and/or
dermatitis. Absorption into the body may cause cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood). May cause gastrointestinal irritation with nausea,
vomiting and diarrhea. May cause liver and kidney damage. May cause hemorrhaging of
the digestive tract. May cause alopecia (loss of hair). May cause cardiopulmonary system
effects. Human fatalities have been reported from acute poisoning. Ingested thallium
compounds are extremely toxic, causing convulsions, coma, conjunctivitis, runny nose,
polyneuritis, motor and sensory peripheral neuropathy, encephalopathy, arterial
hypertension, rapid heart rate, and skin eruptions. May cause dyspnea (difficult or labored
breathing). May cause corneal irritation, dyspnea (labored breathing), bronchospasm, chest
pain, and pulmonary edema, which may be fatal. The toxicological properties have not been
fully investigated

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not empty into drains. Do not flush into surface water or sanitary sewer system.
Persistence and Degradability: No data available
Bioaccumulation/ Accumulation: No data available.
Mobility: No data available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

SECTION 14. TRANSPORT INFORMATION

DOT
UN-No: UN1707
Proper Shipping Name: THALLIUM COMPOUND, N.O.S.
Proper technical name: (THALLOUS MALONATE)
Hazard Class: 6.1
Packing Group: III
TDG
UN-No: UN1707
Proper Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
Packing Group: III
IATA
UN-No: 1707
Proper Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
Packing Group: II
IMDG/IMO
UN-No: 1707
Proper Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
Packing Group: II

SECTION 15. REGULATORY INFORMATION

TSCA
CAS# 2757-18-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
CAS# 2757-18-8: 100 lb TPQ (lower threshold); 10000 lb TPQ (upper thre shold)
SARA Codes
CAS # 2757-18-8: immediate, delayed.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 2757-18-8 can be found on the following state right to know lists: New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+
Risk Phrases:
R 26/28 Very toxic by inhalation and if swallowed.
R 33 Danger of cumulative effects.

Safety Phrases:
S 13 Keep away from food, drink and animal feeding stuffs.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water
.

WGK (Water Danger/Protection)
CAS# 2757-18-8: No data available.
Canada - DSL/NDSL
CAS# 2757-18-8 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of D1A, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 2757-18-8 is listed on the Canadian Ingredient Disclosure List.